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Influence of the Structure of Cetyltrimethylammonium Bromide Based Microemulsions on Base Hydrolysis of Carboxylic Acid Esters

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Abstract

The structure of water/cetyltrimethylammonium bromide/n-butanol/hexane microemulsions was studied by conductometry, viscometry, and Fourier transform 1H NMR spectroscopy with pulse magnetic field gradient. The regions of phase inversion from inverse micelles in hexane through a bicontinual structure to a dispersion of normal micelles in water were determined. The influence of the structure of the microemulsions on the rate of hydrolysis of carboxylic acid p-nitrophenyl esters was analyzed. The hydrolysis rate constants considerably increase in going from inverse to normal microemulsions.

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Authors and Affiliations

  1. Kazan Institute of Biochemistry and Biophysics, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    Yu. F. Zuev, A. B. Mirgorodskaya, L. A. Kudryavtseva, B. Z. Idiyatullin & R. N. Khamidullin

  2. Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center, Russian Academy of Sciences, Kazan, Tatarstan, Russia

    Yu. F. Zuev, A. B. Mirgorodskaya, L. A. Kudryavtseva, B. Z. Idiyatullin & R. N. Khamidullin

Authors
  1. Yu. F. Zuev
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  2. A. B. Mirgorodskaya
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  3. L. A. Kudryavtseva
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  4. B. Z. Idiyatullin
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  5. R. N. Khamidullin
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Zuev, Y.F., Mirgorodskaya, A.B., Kudryavtseva, L.A. et al. Influence of the Structure of Cetyltrimethylammonium Bromide Based Microemulsions on Base Hydrolysis of Carboxylic Acid Esters. Russian Journal of General Chemistry 74, 1051–1056 (2004). https://doi.org/10.1023/B:RUGC.0000045863.38879.c8

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  • DOI: https://doi.org/10.1023/B:RUGC.0000045863.38879.c8

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