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Hydrosilylation of Vinylsiloxanes with Hydrosiloxanes in the Presence of Thermo- and Photoactivated Platinum(II) Phosphine Complexes

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Abstract

Catalytic properties of thermo- and photoactivated platinum complexes [Pt(R2R'X)2Cl2] (X = P, R = Me, R' = Ph; X = P, As, Sb, R = R' = Ph or Bu) in hydrosilylation of vinylsiloxanes with hydrosiloxanes were studied. The neutral ligands were ranked in terms of their effect on the activity of the catalysts. A mechanism of hydrosilylation was proposed.

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  1. St. Peterburg State Institute of Technology, St. Petersburg, Russia

    D. A. de Vekki & N. K. Skvortsov

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  1. D. A. de Vekki
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de Vekki, D.A., Skvortsov, N.K. Hydrosilylation of Vinylsiloxanes with Hydrosiloxanes in the Presence of Thermo- and Photoactivated Platinum(II) Phosphine Complexes. Russian Journal of General Chemistry 74, 197–206 (2004). https://doi.org/10.1023/B:RUGC.0000025500.70902.cd

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