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Reactions of Sulfenyl, Sulfinyl, and Sulfonyl Halides with Conjugated Dienes and Enynes. Synthesis of Unsaturated Sulfides, Sulfoxides, and Sulfones

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Abstract

The reactivities of sulfenyl, sulfinyl, sulfonyl halides in additions to conjugated dienes'enynes, and their derivatives are compared. Despite the fact that all these reactions involve cleavage offormally similar S-Cl bonds, the addition direction and rate depend on the structure of the reactants (dienes and enynes; organosulfur acid chlorides).

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    M. D. Stadnichuk

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Stadnichuk, M.D. Reactions of Sulfenyl, Sulfinyl, and Sulfonyl Halides with Conjugated Dienes and Enynes. Synthesis of Unsaturated Sulfides, Sulfoxides, and Sulfones. Russian Journal of General Chemistry 73, 1751–1768 (2003). https://doi.org/10.1023/B:RUGC.0000018652.23614.4d

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