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Features of the synthesis of unsaturated sulfides proceeding from (2-chloroprop-2-en-1-yl)isothiouronium chloride

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Abstract

Procedure of synthesis of sulfides containing a chloropropenyl fragment sensitive to bases was modified. The change in the sequence of reagents addition ensuring a contact of isothiouronium salt with a minimal base quantity and the application of a mixture hydrazine hydrate-alkali allowed the preparation of target sulfides under mild conditions in up to 93% yields.

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Authors and Affiliations

  1. Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia

    E. P. Levanova, V. S. Vakhrina, V. A. Grabel’nykh, I. B. Rozentsveig, N. V. Russavskaya, A. I. Albanov, E. R. Sanzheeva & N. A. Korchevin

Authors
  1. E. P. Levanova
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  2. V. S. Vakhrina
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  3. V. A. Grabel’nykh
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  4. I. B. Rozentsveig
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  5. N. V. Russavskaya
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  6. A. I. Albanov
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  7. E. R. Sanzheeva
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  8. N. A. Korchevin
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Corresponding author

Correspondence to E. P. Levanova.

Additional information

Original Russian Text © E.P. Levanova, V.S. Vakhrina, V.A. Grabel’nykh, I.B. Rozentsveig, N.V. Russavskaya, A.I. Albanov, E. R. Sanzheeva, N.A. Korchevin, 2015, published in Zhurnal Organicheskoi Khimii, 2015, Vol. 51, No. 2, pp. 175–180.

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Levanova, E.P., Vakhrina, V.S., Grabel’nykh, V.A. et al. Features of the synthesis of unsaturated sulfides proceeding from (2-chloroprop-2-en-1-yl)isothiouronium chloride. Russ J Org Chem 51, 161–166 (2015). https://doi.org/10.1134/S1070428015020037

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  • DOI: https://doi.org/10.1134/S1070428015020037

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