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Boron Difluoride β-Diketonates: IV. Reaction of p-Alkyl-substituted Benzoylacetonates with N-Bromosuccinimide

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Abstract

Bromination of p-alkyl-substituted boron difluoride and chromium(III) benzoylacetonates with N-bromosuccinimide was studied. It was found that that the boron difluoride complexes are selectively brominated by the alkyl radical, whereas chromium toluoylacetonate, by the central carbon atom of the chelate ring.

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Authors and Affiliations

  1. Institute of Chemistry, Far-East Division, Russian Academy of Sciences, Vladivostok, Russia

    E. V. Gukhman & V. A. Reutov

  2. Institute of Chemistry and Applied Ecology, Far-East State University, Vladivostok, Russia

    E. V. Gukhman & V. A. Reutov

Authors
  1. E. V. Gukhman
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  2. V. A. Reutov
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Gukhman, E.V., Reutov, V.A. Boron Difluoride β-Diketonates: IV. Reaction of p-Alkyl-substituted Benzoylacetonates with N-Bromosuccinimide. Russian Journal of General Chemistry 73, 1578–1580 (2003). https://doi.org/10.1023/B:RUGC.0000016026.56938.f2

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  • DOI: https://doi.org/10.1023/B:RUGC.0000016026.56938.f2

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