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Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates

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Abstract

Fluorine-containing aryldihalogenoboranes have been obtained by the reaction of boron and aluminum chlorides and bromides with potassium aryltrifluoroborates K[ArBF3] under mild conditions. In a similar way, bis(pentafluorophenyl)halogenoboranes have been synthesized by the reaction with K[(C6F5)2BF2]. The reaction of K[C6F5BF3] with AlBr3 affords a mixture of C6F5BF2 and C6F5BCl2 due to fast conversion of AlBr3 to AlBrCl2. The inductive and resonance parameters of BCl2 and BBr2 groups were calculated.

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Funding

This work was supported by the Ministry of Science and High Education of Russian Federation within the State task of N.N. Vorozhtsov Institute of Organic Chemistry, Siberian Branch of Russian Academy of Sciences, and G.K. Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Sciences. The authors are grateful to Chemical Research Center for Collective Use of Siberian Branch of Russian Academy of Sciences for spectral and analytical measurements.

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Authors and Affiliations

  1. N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090, Russia

    V. V. Bardin

  2. Federal Research Center “G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,”, Novosibirsk, 630090, Russia

    S. A. Prikhod’ko, M. M. Shmakov, A. Yu. Shabalin & N. Yu. Adonin

Authors
  1. V. V. Bardin
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  2. S. A. Prikhod’ko
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  3. M. M. Shmakov
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  4. A. Yu. Shabalin
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  5. N. Yu. Adonin
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Corresponding author

Correspondence to V. V. Bardin.

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Conflict of Interest

No conflict of interest was declared by the authors.

Russian Text © The Author(s), 2020, published in Zhurnal Obshchei Khimii, 2020, Vol. 90, No. 1, pp. 72–84.

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Bardin, V.V., Prikhod’ko, S.A., Shmakov, M.M. et al. Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates. Russ J Gen Chem 90, 50–61 (2020). https://doi.org/10.1134/S1070363220010089

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  • DOI: https://doi.org/10.1134/S1070363220010089

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