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Hydrolysis of Chloro(silyl)olefins in Neutral and Acidic Media

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Abstract

Action of water on chloro[chloro(alkoxy)silyl]olefins with various number of chlorines in the unsaturated moiety was studied in acidic and neutral media. Linear and cyclic oligosiloxanes with unsaturated chlorine-containing groups were obtained. Correlation between the hydrolytic stability of the Si-Csp 2 bond and the structure of the starting chlorosilylolefin was explored.

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Authors and Affiliations

  1. Gosudarstvennyi nauchno-issledovatel'skii institut khimii i tekhnologii elementoorganicheskikh soedinenii State Research Center of the Russian Federation, Moscow, Russia

    V. G. Lakhtin, V. D. Sheludyakov, P. V. Ivanov, N. P. Telegina & E. A. Chernyshev

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  1. V. G. Lakhtin
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  2. V. D. Sheludyakov
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  3. P. V. Ivanov
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  4. N. P. Telegina
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  5. E. A. Chernyshev
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Lakhtin, V.G., Sheludyakov, V.D., Ivanov, P.V. et al. Hydrolysis of Chloro(silyl)olefins in Neutral and Acidic Media. Russian Journal of General Chemistry 73, 1535–1538 (2003). https://doi.org/10.1023/B:RUGC.0000016016.77748.97

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  • DOI: https://doi.org/10.1023/B:RUGC.0000016016.77748.97

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