Abstract
Results on the paper's theme are reviewed. Attention is focused mainly on the use of transients of current and open-circuit potential for elucidating changes in the structure of the electrical double layer (EDL) caused by the CO adsorption. It is shown that the high binding energy of CO with surfaces of platinum metals leads to a strong suppression of the total differential capacitance of the electrode, the recharge of the surface, the displacement of strongly adsorbed atoms formed during the adsorption of ions with a total charge transfer, and to other alterations in the EDL plates facing both solution and metal. The importance of allowing for “double-layer” effects when solving problems of electrocatalysis on platinum metals is emphasized.
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REFERENCES
Langmuir, I., Trans. Faraday Soc., 1922, vol. 17, p. 621.
Frumkin, A.N., Potentsialy nulevogo zaryada (The Potentials of Zero Charge), Moscow: Nauka, 1979.
Elektrodnye protsessy v rastvorakh organicheskikh soedinenii (The Electrode Processes in Solutions of Organic Compounds), Damaskin, B.B., Ed., Moscow: Mosk. Gos. Univ., 1985.
Damaskin, B.B., Petrii, O.A., and Tsirlina, G.A., Elektrokhimiya (The Electrochemistry), Moscow: Khimiya, 2001.
Kazarinov, V.E. and Mansurov, G.I., Elektrokhimiya, 1966, vol. 2, p. 1338.
Frumkin, A.N., Kazarinov, V.E., and Tysyachnaya, G. Ya., Dokl. Akad. Nauk SSSR, 1971, vol. 198, p. 145.
Stenin, V.F., Tysyachnaya, G.Ya., Podlovchenko, B.I., and Kazarinov, V.E., Elektrokhimiya, 1971, vol. 7, p. 1384.
Gilman, S., J. Phys. Chem., 1967, vol. 71, pp. 4330, 4339.
Breiter, M.W., J. Electroanal. Chem., 1983, vol. 157, p. 327; 1984, vol. 180, p. 25.
Sobkowski, J. and Gzerwinski, A., J. Phys. Chem., 1985, vol. 89, p. 365.
Beden, B., Lamy, C., de Tracconi, N.R., and Arvia, J., Electrochim. Acta, 1990, vol. 35, p. 691.
Orts, J.M., Fernandez-Vega, A., Feliu, J.M., Aldaz, A., and Clavilier, J., J. Electroanal. Chem., 1992, vol. 327, p. 261.
Orts, J.M., Gomez, R., Feliu, J.M., and Clavilier, J., Electrochim. Acta, 1994, vol. 39, p. 1519.
Clavilier, J., Orts, J.M., Gomez, R., Feliu, J.M., and Aldaz, A., J. Electroanal. Chem., 1996, vol. 404, p. 281.
Weaver, M.J., Langmuir, 1998, vol. 14, p. 3932.
Podlovchenko, B.I. and Gladysheva, T.D., Elektrokhimiya, 1998, vol. 34, p. 280.
Frumkin, A.N., Petrii, O.A., and Damaskin, B.B., J Electroanal. Chem., 1970, vol. 27, p. 81.
Frumkin, A.N. and Petrii, O.A., Electrochim. Acta., 1975, vol. 20, p. 347.
Frumkin, A.N., Petrii, O.A., and Damaskin, B.B., in Comprehensive Treatise of Electrochemistry, Bockris, J.O'M., Conway, B.E., and Yeager, E., Eds., New York: Plenum, 1980, vol. 1, p. 221.
Podlovchenko, B.I., Elektrokhimiya, 2000, vol. 36, p. 931.
Podlovchenko, B.I. and Kolyadko, E.A., J. Electroanal. Chem., 2001, vol. 506, p. 11..
Podlovchenko, B.I., Gladysheva, T.D., and Smolin, A.V., Mendeleev Commun., 1999, vol. 3, p. 97.
Podlovchenko, B.I. and Gladysheva, T.D., Elektrokhimiya, 2001, vol. 37, p. 901.
Podlovchenko, B.I. and Gladysheva, T.D., Elektrokhimiya, 2002, vol. 38, p. 399.
Podlovchenko, B.I. and Gladysheva, T.D., Elektrokhimiya, 2002, vol. 38, p. 625.
Podlovchenko, B.I. and Gladysheva, T.D., Elektrokhimiya, 2003, vol. 39, p. 880.
Podlovchenko, B.I., Gladysheva, T.D., and Kolyadko, E.A., J. Electroanal. Chem., 2003, vol. 552, p. 85.
Kolb, D., in Advances in Electrochemistry and Electro-chemical Engineering, Gerischer, H., Ed., New York: Wiley Interscience, 1978, vol. 11, p. 125.
Petrii, O.A. and Lapa, A.S., Itogi Nauki Tekh., Ser: Elektrokhim., 1987, vol. 24, p. 94.
Podlovchenko, B.I., in Problemy sovremennogo kataliza na metallakh (Current Problems of Catalysis on Metals), Zakumbaeva, G.D., Ed., Almaty: Gylym, 1994, p. 200.
Breiter, M.W., J. Electroanal. Chem., 1969, vol. 23, p. 173.
Smolin, A.V. and Podlovchenko, B.I., Elektrokhimiya, 1998, vol. 34, p. 287.
Gladysheva, T.D. and Podlovchenko, B.I., Elektrokhimiya, 1999, vol. 35, p. 573.
Zurawski, D., Rice, L., Hourani, M., and Wieckowski, A., J. Electroanal. Chem., 1987, vol. 230, p. 221.
Hourani, M. and Wieckowski, A., J. Electroanal. Chem., 1987, vol. 227, p. 259.
Kim, J.-G., Baricuatro, J.H., Soriaga, M.P., and Suggs, D.W., J. Electroanal. Chem., 2001, vol. 509, p. 170.
Podlovchenko, B.I. and Kolyadko, E.A., Elektrokhimiya, 2003, vol. 39, p. 915.
Podlovchenko, B.I. and Petukhova, R.I., Elektrokhimiya, 1969, vol. 5, p. 380.
Khazova, O.A., Vasil'ev, Yu.B., and Bagotskii, V.S., Elektrokhimiya, 1970, vol. 6, p. 1367.
Podlovchenko, B.I., Manzhos, R.A., and Maksimov, Yu.M., Elektrokhimiya, 2002, vol. 38, p. 1430.
Frumkin, A.N. and Petrii, O.A., Dokl. Akad. Nauk SSSR, 1971, vol. 196, p. 1387.
Kazarinov, V.E., Petrii, O.A., Topolev, V.V., and Losev, A.V., Elektrokhimiya, 1971, vol. 7, p. 1365.
Gomez, R., Orts, J.M., Feliu, J.M., Clavilier, J., and Klein, L.N., J. Electroanal. Chem., 1997, vol. 432, p. 1.
Czerwinski, A., J. Electroanal. Chem., 1994, vol. 379, p. 487.
Climent, V., Gomez, R., and Feliu, J.M., Electrochim. Acta, 1999, vol. 45, p. 629.
Gomez, R., Feliu, J.M., Aldaz, A., and Weaver, M.J., Surf. Sci., 1998, vol. 410, p. 48.
Maksimov, Yu.M. and Podlovchenko, B.I., Elektrokhimiya, 2003, vol. 2004.
Watanabe, M., Shibata, M., and Motoo, S., J. Electroanal. Chem., 1985, vol. 187, p. 161.
Watanabe, M. and Motoo, S., J. Electroanal. Chem., 1985, vol. 194, p. 261.
Kunimatsu, K., Lezna, R.O., and Enyo, M., J. Electroanal. Chem., 1989, vol. 258, p. 115.
Podlovchenko, B.I. and Kolyadko, E.A., Elektrokhimiya, 2000, vol. 36, p. 1433.
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Podlovchenko, B.I. Electrical Double Layer Structure on Electrodes of Platinum Metals: Effect of the Carbon Monoxide Adsorption. Russian Journal of Electrochemistry 40, 1132–1140 (2004). https://doi.org/10.1023/B:RUEL.0000048644.51179.9c
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DOI: https://doi.org/10.1023/B:RUEL.0000048644.51179.9c