Abstract
Spectroelectrochemical properties of poly-o-phenylenediamine (PPD) and the synthesized composite of PPD and polyaniline—two chemically related polymers containing an amino-substituted benzene ring but having different conduction nature—are studied. The polyaniline synthesis on PPD-modified electrodes involves stages of the reaction initiation, the copolymer formation, and the formation of a polyaniline layer at the copolymer/solution interface.
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REFERENCES
Das, B., Kar, S., Chakraborty, S., Chakraborty, D., and Gangopadhyay, S., J. Appl. Polym. Sci., 1998, vol. 69, p. 841.
Sanches De Pinto, M.I., Mishima, H.T., and Lopez, B.A., J. Appl. Electrochem., 1997, vol. 27, p. 831.
Malinauskas, A., Bron, M., and Holze, R., Synth. Met., 1998, vol. 92, p. 127.
Sacak, M., Akbulut, U., and Batchelder, D.N., Polymer, 1998, vol. 39, p. 4735.
Latonen, R-M., Kvamstrom, C., and Ivaska, A., Synth. Met., 2001, vol. 119, p. 83.
Talu, M., Kabasakaloglu, M., and Oskoui, H.R., J. Polym. Sci., Part A: Polym. Chem., 1996, vol. 34, p. 298.
Morales, J., Olayo, M.G., Cruz, G.J., Olayo, R., J. Polym. Sci., Part B: Polym. Phys., 2002, vol. 40, p. 1850.
Sari, B. and Talu, M., Synth. Met., 1998, vol. 94, p. 221.
Yohannes, T., Carlberg, J.C., Inganas, O., and Solomon, T., Synth. Met., 1997, vol. 88, p. 15.
Catellani, M., Luzzati, S., Mendichi, R., Schieroni, A.G., and Stein, P.C., Polymer, 1996, vol. 37, p. 1059.
Wang, Y.Z., Gebler, D.D., Fu, D.K., Swager, T.M., and Epstein, A.J., Appl. Phys. Lett., 2002, vol. 70, p. 3215.
Hillman, A.R. and Glidle, A., Phys. Chem. Chem. Phys., 2001, vol. 3, p. 3447.
Soavi, F., Arbizzani, C., and Mastragostino, M., Phys. Chem. Chem. Phys., 2000, vol. 002, p. 2993.
Ng., S.C., Xu, J.M., Hardy, S., and Chan, O., Synth. Met., 2000, vol. 110, p. 31.
Golovtsov, I. and Opik, A., Synth. Met., 2001, vol. 121, p. 1363.
Hillman, A.R. and Mallen, E.F., J. Eleciroanal. Chem., 1990, vol. 281, p. 109.
Zotti, G., Musiani, M., Zecchin, S., and Schiavon, G., Chem. Mater., 1998, vol. 10, p. 480.
Demelo, C.P., Dossantos, C.G., Silva, A.M., Dossantos, F.L., and Desouza, J.E., Mol. Cryst. Liquid Cryst., 2002, vol. 374, p. 543.
Fu., M.X., Chen, F., Zhang, J.X., and Shi, G.Q., J. Mater. Chem., 2002, vol. 12, p. 2331.
Somani, P. and Radhakrishnan, S., Mater. Chem. Phys., 2002, vol. 76, p. 15.
Jelle, B.P., Hagen, G., and Birketveit, O., J. Appl. Electrochem., 1998, vol. 28, p. 483.
Jelle, B.P. and Hagen, G., J. Appl. Electrochem., 1998, vol. 29, p. 1061.
Alpatova, N.M., Ovsyannikova, E.V., Grosheva, M.Yu., Topolev, V.V., Kirchmeyer, S., Jonas, F., Bazhenov, V.M., and Nikanorov, V.A., Synth. Met., 2003, vol. 138, p. 507.
Pisarevskaya, E.Yu., Nekrasov, A.A., and Alpatova, N.M., Elektrokhimiya (in press).
Levi, M.D. and Pisarevskaya, E.Yu., Electrochim. Acta, 1992, vol. 37, p. 635.
Pisarevskaya, E.Yu. and Levi, M.D., Elektrokhimiya, 1994, vol. 30, p. 50.
Pisarevskaya, E.Yu. and Levi, M.D., Elektrokhimiya, 1994, vol. 30, p. 54.
Vorotyntsev, M.A., Daikhin, L.I., and Levi, M.D., J. Electroanal. Chem., 1992, vol. 332, p. 213.
Komura, T., Yamaguti, T., and Takahashi, K., Electrochim. Acta, 1996, vol. 41, p. 2865.
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Pisarevskaya, E.Y., Ovsyannikova, E.V. & Alpatova, N.M. Two-Layered Poly-o-phenylenediamine/Polyaniline Composite: Electrosynthesis and Spectroelectrochemical Properties. Russian Journal of Electrochemistry 40, 969–976 (2004). https://doi.org/10.1023/B:RUEL.0000041365.17498.ef
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DOI: https://doi.org/10.1023/B:RUEL.0000041365.17498.ef