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Polarization Curve of a Porous Hydrophobized Electrode for Electrosynthesis Involving a Side Electrochemical Reaction

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Abstract

A polarization curve, suggested for electrosynthesis in a porous hydrophobized electrode operating in an inner-kinetic mode at a current efficiency for the target product below 100%, depends on the balance between exchange currents and slopes of the side and target reactions and the difference between the equilibrium potential of the side reaction and the steady-state electrode potential. At different slopes of the side and the target reactions, the current efficiency depends on the polarization. Experimental and calculated data satisfactory agree.

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Authors
  1. Yu. V. Saltykov
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  2. V. L. Kornienko
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Saltykov, Y.V., Kornienko, V.L. Polarization Curve of a Porous Hydrophobized Electrode for Electrosynthesis Involving a Side Electrochemical Reaction. Russian Journal of Electrochemistry 40, 716–720 (2004). https://doi.org/10.1023/B:RUEL.0000035254.63589.6f

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  • DOI: https://doi.org/10.1023/B:RUEL.0000035254.63589.6f

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