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Limiting Current of Copper Electrodeposition from a Copper Sulfate Solution under Conditions of Natural Convection: The Space Charge Effect

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Abstract

Copper electrodeposition from a copper sulfate solution under conditions of natural convection is analyzed theoretically and examined experimentally. The space charge, which forms in the near-cathode layer, is shown to affect the limiting current density and to change its concentration dependence.

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Authors and Affiliations

  1. Frumkin Institute of Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119071, Russia

    A. P. Grigin, L. A. Reznikova, N. N. Tomashova & A. D. Davydov

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  1. A. P. Grigin
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  2. L. A. Reznikova
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  3. N. N. Tomashova
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  4. A. D. Davydov
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Grigin, A.P., Reznikova, L.A., Tomashova, N.N. et al. Limiting Current of Copper Electrodeposition from a Copper Sulfate Solution under Conditions of Natural Convection: The Space Charge Effect. Russian Journal of Electrochemistry 40, 633–638 (2004). https://doi.org/10.1023/B:RUEL.0000032013.18818.d4

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  • DOI: https://doi.org/10.1023/B:RUEL.0000032013.18818.d4

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