Abstract
The connection of the hydrogen diffusion flux through a steel membrane and the fraction of adsorbed hydrogen removed due to the absorption in the metal with the cathodic polarization of the working membrane side and the hydrogen evolution rate in ethylene glycol solutions of HCl (0.05–0.99 M) with a constant ionic force containing 0.5–10 mM of As(V) in the form of H3AsO4 is studied.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
REFERENCES
Devanathan, M.A.V. and Stachurski, Z., J. Electrochem. Soc., 1964, vol. 11, p. 619.
Boes, N. and Zuchner, H., J. Less-Common Met., 1976, vol. 49, p. 223.
Chernenko, V.N. and Yakunina, T.G., Elektrokhimiya, 1982, vol. 18, p. 904.
Kudryavtsev, V.N., Balakin, Yu.P., and Vagramyan, N.T., Zashch. Met., 1965, vol. 1, p. 477.
Vigdorovich, V.I., Tsygankova, L.E., and D'yachkova, T.P., Khim. Khim. Tekhnol., 2001, vol. 44, p. 80.
Vigdorovich, V.I., Tsygankova, L.E., and D'yachkova, T.P., Zashch. Met., 2002, vol. 38, p. 514.
Vigdorovich, V.I. and Agladze, T.R., Elektrokhimiya, 1975, vol. 11, p. 85.
Vigdorovich, V.I., Tsygankova, L.E., and D'yachkova, T.P., Elektrokhimiya, 2002, vol. 38, p. 719.
Kardash, N.V. and Batrakov, V.V., Zashch. Met., 1995, vol. 31, p. 441.
Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie reaktivy (Pure Chemical Reagents), Moscow: Khimiya, 1974.
Levin, A.I. and Pomosov, A.V., Laboratornyi praktikum po teoreticheskoi elektrokhimii (A Laboratory Course in Theoretical Electrochemistry), Moscow: Metallurgiya, 1966.
Frumkin, A.N., Bagotzky, V.S., Iofa, Z.A., and Kabanov, B.N., Kinetika elektrodnykh protsessov (The Electrode Kinetics), Moscow: Mosk. Gos. Univ., 1952.
Vigdorovich, V.I., D'yachkova, T.P., Pupkova, O.L., and Tsygankova, L.E., Elektrokhimiya, 2001, vol. 37, p. 1437.
Ekilik, V.V. and Grigor'ev, V.P., Priroda rastvoritelya i zashchitnoe deistvie ingibitorov korrozii (The Solvent Nature and the Protective Action of Corrosion Inhibitors), Rostov-on-Don: Rostov. Gos. Univ., 1984.
Spravochnik khimika (A Chemist's Handbook), Nikol'skii, B.P., Ed., Moscow: Khimiya, 1964, vol. 3.
Vigdorovich, V.I., Tsygankova, L.E., and Kopylova, E.Yu., Elektrokhimiya, 2003, vol. 39, p. 836.
Izmailov, N.A., Elektrokhimiya rastvorov (The Electrochemistry of Solutions), Moscow: Khimiya, 1976.
Kreshkov, A.P., Bykova, L.N., and Kazaryan, N.A., Kislotno-osnovnoe titrovanie v nevodnykh rastvorakh (Acid-Base Titration in Nonaqueous Solutions), Moscow: Khimiya, 1967.
Vigdorovich, M.V. and Pupkova, O.L., Inzh.-Fiz. Zh., 2001, vol. 74, p. 137.
Vigdorovich, M.V., Zh. Fiz. Khim., 2003, vol. 77, p. 946.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Vigdorovich, V.I., Kopylova, E.Y. Effect of Cathodic Polarization on the Hydrogen Diffusion through a Steel Membrane from Ethylene Glycol Solutions of HCl Containing As(V). Russian Journal of Electrochemistry 40, 153–157 (2004). https://doi.org/10.1023/B:RUEL.0000016328.79260.cf
Issue Date:
DOI: https://doi.org/10.1023/B:RUEL.0000016328.79260.cf