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Unexpected formation of clusters with a nortricyclene-containing carborane ligand, 1-(η6-arene)-3-(C7H9CH2O)-isonido-1,2,4-RuC2B8H9, in the reaction of 1,1,3-(PPh3)3-1-H-1,2,4-RuC2B8H9 with 2-(hydroxymethyl)norbornadiene in arene solvents

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Abstract

Heating of 1,1,3-(PPh3)3-1-H-1,2,4-RuC2B8H9 with 2-(hydroxymethyl)bicyclo[2.2.1]hepta-2,5-diene in arene solvents (benzene, toluene, or mesitylene) unexpectedly afforded the ruthenium arene complexes 1-(η6-arene)-3-(C7H9CH2O)-isonido-1,2,4-RuC2B8H9 containing the nortricyclene fragment in the carborane ligand.

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References

  1. L. I. Zakharkin, I. T. Chizhevsky, G. G. Zhigareva, P. V. Petrovskii, A. V. Polyakov, A. I. Yanovsky, and Yu. T. Struchkov, J. Organomet. Chem., 1988, 358, 449.

    Google Scholar 

  2. I. T. Chizhevsky, G. G. Zhigareva, P. V. Petrovskii, and L. I. Zakharkin, Metalloorg. Khim., 1992, 5, 625 [Organomet. Chem. USSR, 1992, 5, 301 (Engl. Transl.)].

    Google Scholar 

  3. R. T. Beker, V. S. Delaney, R. E. King III, C. B. Knobler, J. A. Long, T. B. Marder, T. E. Paxson, R. G. Teller, and M. F. Hawthorne, J. Am. Chem. Soc., 1984, 106, 2965.

    Google Scholar 

  4. A. Felekidis, M. Goblet-Stachow, J. F. Liégeois, B. Pirotte, J. Delarge, A. Demonceau, M. Fontaine, A. F. Noels, I. T. Chizhevsky, T. V. Zinevich, V. I. Bregadze, F. M. Dolgushin, and Yu. T. Struchkov, J. Organomet. Chem., 1997, 536–537, 405.

    Google Scholar 

  5. W. Jung and M. F. Hawthorne, J. Am. Chem. Soc., 1980, 102, 3024.

    Google Scholar 

  6. V. E. Konoplev, I. V. Pisareva, D. A. Lemenovskii, P. V. Petrovskii, O. L. Tok, F. M. Dolgushin, and I. T. Chizhevsky, Collect. Czech. Chem. Commun., 2002, 67, 936.

    Google Scholar 

  7. J. D. Kennedy, in Multinuclear NMR (NMR in Inorganic and Organometallic Chemistry), Ed. J. Mason, Plenum, New York-London, 1987, Ch. 8, p. 221.

    Google Scholar 

  8. T. P. Hanusa, J. C. Huffman, and L. J. Todd, Polyhedron, 1982, 1, 77.

    Google Scholar 

  9. R. G. Swisher, E. Sinn, and R. N. Grimes, Organometallics, 1983, 2, 506.

    Google Scholar 

  10. G. C. Levy and G. L. Nelson, Carbon-13 Nuclear Magnetic Resonance for Organic Chemists, Wiley, New York, 1972, 222 pp.

    Google Scholar 

  11. B. Štibr, J. Plešek, and A. Zobáč ová, Polyhedron, 1982, 1, 824.

    Google Scholar 

  12. M. Bown, B. Grüner, B. Štibr, X. L. R. Fontain, M. Thornton-Pett, and J. D. Kennedy, J. Organomet. Chem., 2000, 614–615, 269.

    Google Scholar 

  13. T. V. Zinevich, P. V. Petrovskii, F. M. Dolgushin, A. I. Yanovsky, and I. T. Chizhevsky, Izv. Akad. Nauk, Ser. Khim., 2001, 484 [Russ. Chem. Bull., Int. Ed., 2001, 50, 504].

    Google Scholar 

  14. M. Bown, R. Fontain, N. N. Greenwood, J. D. Kennedy, and M. Thornton-Pett, J. Chem. Soc., Dalton Trans., 1990, 3039.

  15. I. V. Pisareva, F. M. Dolgushin, O. L. Tok, V. E. Konoplev, K. Yu. Suponitsky, A. I. Yanovsky, and I. T. Chizhevsky, Organometallics, 2001, 20, 4216.

    Google Scholar 

  16. O. Volkov, R. Macías, N. P. Rath, and L. Barton, J. Organomet. Chem., 2002, 657, 40.

    Google Scholar 

  17. O. Volkov, N. P. Rath, and L. Barton, Organometallics, 2003, 22, 2548.

    Google Scholar 

  18. K. Nestor, X. L. R. Fontaine, N. N. Greenwood, J. D. Kennedy, J. Plešek, B. Štíbr, and M. Thornton-Pett, Inorg. Chem., 1989, 28, 2219.

    Google Scholar 

  19. S. V. Timofeev, I. A. Lobanova, P. V. Petrovskii, Z. A. Starikova, and V. I. Bregadze, Izv. Akad. Nauk, Ser. Khim., 2001, 1604 [Russ. Chem. Bull., Int. Ed., 2001, 50, 1683].

    Google Scholar 

  20. I. T. Chizhevsky, Dr. Sc. (Chem.) Thesis, A. N. Nesmeyanov Institute of Organoelement Compounds of the Russian Academy of Sciences, Moscow, 1999, p. 96 (in Russian).

  21. A. Walker, C. B. Knobler, and M. F. Hawthorne, J. Am. Chem. Soc., 1983, 105, 3368.

    Google Scholar 

  22. I. T. Chizhevsky, N. V. Rastova, N. E. Kolobova, L. E. Vinogradova, and L. A. Leites, Izv. Akad. Nauk SSSR, Ser. Khim., 1985, 1382 [Bull. Acad. Sci. USSR, Div. Chem. Sci., 1985, 34, 1263 (Engl. Transl.)].

  23. G. J. Kubas, in Dihydrogen and δBond Complexes, Kluwer Academic-Plenum Press, New York, 2001.

    Google Scholar 

  24. M. Peruzzini and P. Poli, in Recent Advances in Hydride Chemistry, Elsevier, Amsterdam, The Netherlands, 2001.

    Google Scholar 

  25. S. A. Jackson, P. M. Hodges, M. Poliakoff, J. J. Turner, and F.-W. Grevels, J. Am. Chem. Soc., 1990, 112, 1221.

    Google Scholar 

  26. S. A. Jackson, P. M. Hodges, M. Polyakoff, J. J. Turner, and F.-W. Grevels, J. Am. Chem. Soc., 1990, 112, 1234.

    Google Scholar 

  27. G. Jia, W. S. Ng, and C. P. Lau, Organometallics, 1998, 17, 4538.

    Google Scholar 

  28. S. H. Liu, X. Huang, W. S. Ng, T. B. Wen, M. F. Lo, Z. Y. Zhou, I. D. Williams, Z. Lin, and G. Jia, Organometallics, 2003, 22, 904.

    Google Scholar 

  29. M. Green, J. A. K. Howard, A. P. James, C. M. Nunn, and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1987, 61.

  30. P. J. Graham, E. L. Buhle, and N. Pappas, J. Org. Chem., 1961, 26, 4658.

    Google Scholar 

  31. G. M. Sheldrick, SHELXTL-97 V5.10, Bruker AXS Inc., Madison, WI-53719, USA, 1997.

    Google Scholar 

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Authors and Affiliations

  1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation

    V. E. Konoplev, F. M. Dolgushin, I. V. Pisareva, E. V. Vorontsov & I. T. Chizhevsky

  2. Department of Chemistry, M. V. Lomonosov Moscow State University, Leninskie Gory, 119992, Moscow, Russian Federation

    D. A. Lemenovskii

Authors
  1. V. E. Konoplev
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  2. F. M. Dolgushin
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  3. I. V. Pisareva
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  4. E. V. Vorontsov
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  5. D. A. Lemenovskii
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  6. I. T. Chizhevsky
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Konoplev, V.E., Dolgushin, F.M., Pisareva, I.V. et al. Unexpected formation of clusters with a nortricyclene-containing carborane ligand, 1-(η6-arene)-3-(C7H9CH2O)-isonido-1,2,4-RuC2B8H9, in the reaction of 1,1,3-(PPh3)3-1-H-1,2,4-RuC2B8H9 with 2-(hydroxymethyl)norbornadiene in arene solvents. Russian Chemical Bulletin 52, 2732–2739 (2003). https://doi.org/10.1023/B:RUCB.0000019893.92029.55

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  • DOI: https://doi.org/10.1023/B:RUCB.0000019893.92029.55

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