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Complexation in Water-Soluble Systems Poly-N-vinylpyrrolidone-Fullerene C60

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Abstract

Complexes of fullerene C6 0 with poly-N-vinylpyrrolidone were prepared by various procedures in the presence of additional agents in solution (systems C6 0-poly-N-vinylpyrrolidone and ternary system C6 0-tetraphenylporphyrin-poly-N-vinylpyrrolidone) and in the solid phase (C6 0-polyvinylpyrrolidone and C6 0-KBr-poly-N-vinylpyrrolidone). Formation of a donor-acceptor bond in the system C6 0-poly-N-vinylpyrrolidone was studied by 13C NMR. The conditions under which the ternary complex C6 0-tetraphenylporphyrin-poly-N-vinylpyrrolidone with fullerene content varied from 1 to 5 wt % can be obtained were found.

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Authors and Affiliations

  1. Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia

    O. V. Ratnikova, E. Yu. Melenevskaya, M. V. Mokeev & V. N. Zgonnik

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  1. O. V. Ratnikova
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  2. E. Yu. Melenevskaya
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  3. M. V. Mokeev
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  4. V. N. Zgonnik
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Ratnikova, O.V., Melenevskaya, E.Y., Mokeev, M.V. et al. Complexation in Water-Soluble Systems Poly-N-vinylpyrrolidone-Fullerene C60 . Russian Journal of Applied Chemistry 76, 1620–1625 (2003). https://doi.org/10.1023/B:RJAC.0000015725.92998.a3

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  • DOI: https://doi.org/10.1023/B:RJAC.0000015725.92998.a3

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