Abstract
Fe(CN)6 3 - and Fe(CN)6 4 - anions are sorbed from aqueous solutions of their potassium and cesium salts on β-Ni(OH)2 by the mechanism of anion exchange with hydroxy groups. Alkali metal cations (K+, Cs+) are also partly sorbed on nickel(II) hydroxide in the form of anionic complexes (K,Cs) z Fe(CN)6 (n - z)-, where n = 3 or 4 (0 < z < n). The chemical composition of the new phase appearing in contact of nickel(II) hydroxide with aqueous potassium and cesium hexacyanoferrates(II, III) was determined by X-ray phase analysis and IR spectroscopy.
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References
Belinskaya, F.A., in Ionnyi obmen i ionometriya: Mezhvuzovskii sbornik (Ion Exchange and Ionometry): Intercollegiate Coll. of Scientific Works), St. Petersburg: Sankt-Peterb. Gos. Univ., issue 10, 2000, pp. 7–49.
Kornilovich, B.Yu., Abstracts of Papers, XV Mendeleevskii S”ezd po obshchei i prikladnoi khimii: Obninskii Simposium (XV Mendeleev Congr. on General and Applied Chemistry: Obninsk Symp.), Obninsk: Fiziko-Energ. Inst., 1993, vol. 2, p. 104.
Sokolova, M.M., Vol'khin, V.V., and Tomchuk, T.K., in Ochistka vody i stokov: Mezhvuzovskii sbornik (Decontamination of Water and Discharges: Intercollegiate Coll. of Scientific Works), Tomsk: Nauchno-Issled. Inst. Vysokikh Napryazhenii, 1994, pp. 78–83.
Kapustin, A.E., Usp. Khim., 1991., vol. 60, no. 12, pp. 2685–2717.
Kjeldson, P., Water, Air Soil Pollution, 1999, vol. 115, pp. 279–307.
Nishizava, H., Kishikawa, T., and Minami, H., J. Solid State Chem., 1999, vol. 146, pp. 39–46.
Scheinost, A.C. and Sparks, D.L., J. Colloid Interface Sci., 2000, vol. 223, pp. 167–178.
Lur'e, Yu.Yu., Spravochnik po analiticheskoi khimii (Handbook on Analytical Chemistry), Moscow: Khimiya, 1979.
Kolthoff, I.M., Belcher, R, Stenger, V.A., and Matsuyama, G., Volumetric Analysis, vol. III: Titration Methods: Oxidation-Reduction Reactions, New York: Interscience, 1957.
Polyanskii, N.G., Gorbunov, G.V., and Polyanskaya, N.L., Metody issledovaniya ionitov (Techniques for Studying of Ion Exchangers), Moscow: Khimiya, 1976.
Newman, S.P. and Jones, W., J. Solid State Chem., 1999, vol. 148, pp. 26–40.
Tananaev, I.V., Seifer, G.B., Kharitonov, Yu.Ya., et al., Khimiya ferrotsianidov (Chemistry of Ferrocyanides), Moscow: Nauka, 1971.
Khaldi, M., De Roy A., Chaouh, M., and Besse, J.P., J. Solid State Chem., 1997, vol. 130, pp. 66–73.
Houri, B., Legrouri, A., Barroug, A., et al., Coll. Czech. Chem. Commun., 1998, vol. 63, pp. 732–740.
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Nagornyi, O.V., Kolyshkin, A.S. & Vol'khin, V.V. Sorption of Hexacyanoferrate(II, III) Anions on Nickel(II) Hydroxide. Russian Journal of Applied Chemistry 76, 1238–1241 (2003). https://doi.org/10.1023/B:RJAC.0000008292.38249.f4
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DOI: https://doi.org/10.1023/B:RJAC.0000008292.38249.f4