Skip to main content
SpringerLink
Log in

Vanadia impregnated iron-pillared montmorillonite for aniline methylation

  • Published:
Reaction Kinetics and Catalysis Letters Aims and scope Submit manuscript

Abstract

Vanadia impregnated iron-pillared montmorillonites with different weight percentages of vanadia have been prepared. Subsequent characterization by XRD, FT-IR, surface area and pore volume measurements was carried out. Acidity was determined by three independent techniques namely thermogravimetric desorption of 2,6-dimethylpyridine, spectrophotometric monitoring of adsorption of perylene and temperature-programmed desorption of ammonia. Conversion of cumene in the vapor phase has been performed as a test reaction of acidity. Aniline methylation was carried out to check the catalytic efficiency of the solids.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. D.J. Hucknal: Selective Oxidation of Hydrocarbons, Academic Press, London 1974.

    Google Scholar 

  2. J. Villadsen, H. Livberg: Catal. Rev. Sci. Eng., 17, 203 (1978).

    CAS  Google Scholar 

  3. A. Bielanski, J. Haber: Catal. Rev. Sci. Eng., 19, 1 (1979).

    CAS  Google Scholar 

  4. P.L. Villa: in Catalyst Deactivation (Eds. B. Delmon, G. F. Froment), p. 103. Elsevier, Amsterdam 1980

    Google Scholar 

  5. T. Blasco, J. Lopez-Nieto, M.I. Vasquet: J. Catal., 159, 271 (1995).

    Article  Google Scholar 

  6. J.R. Shon, S.G. Cho, Y.I. Pae, S. Hayashi: J. Catal., 159, 170 (1996).

    Article  Google Scholar 

  7. J.M. Lopez-Neito, G. Kremnik, J.L.G. Fiero: Appl. Catal., 61, 235 (1990).

    Article  Google Scholar 

  8. S. Narayanan, K. Deshapande: Micropor. Mater., 11, 77 (1997).

    Article  CAS  Google Scholar 

  9. S. Narayanan, K. Deshapande: Appl. Catal. A. Gen:, 135, 125 (1996).

    Article  CAS  Google Scholar 

  10. Rahna K. Shamsudeen, K. Nisha, S. Sugunan: Ind. J. Chem., 41 A, 2244 (2002).

    CAS  Google Scholar 

  11. T. Mishra, K. Parida: Appl. Catal. A Gen:, 174, 91 (1988).

    Article  Google Scholar 

  12. T. Mishra, K. Parida: Appl. Catal. A Gen:, 166, 123 (1998).

    Article  CAS  Google Scholar 

  13. A. Gil, L.M. Gandia, M.A. Vicente: Catal. Rev. Sci. Eng., 42, 145 (2000).

    Article  CAS  Google Scholar 

  14. T.J. Dines, C.H. Rochester, A.W. Ward: J. Chem. Soc. Farad. Trans., 87, 1611 (1991).

    Article  CAS  Google Scholar 

  15. M. Takalji, T.K. Qwai, M. Soma, Onoshi, K. Tamaru: J. Phys. Chem., 80, 430 (1976).

    Article  Google Scholar 

  16. M. Takalji, T.K. Qwai, Onoshi, K. Tamaru: J. Catal., 50, 441 (1977).

    Article  Google Scholar 

  17. M.M. Khader: J. Mol. Catal. A. Chem., 104, 87 (1995).

    Article  CAS  Google Scholar 

  18. S. Prasad, B.S. Rao: J. Mol. Catal., 62, L 17 (1990).

    Article  Google Scholar 

  19. S. Narayanan, K. Deshpande: Appl. Catal. A. Gen., 193, 17 (2000).

    Article  CAS  Google Scholar 

  20. S. Narayanan, K. Deshpande: Appl. Catal. A. Gen., 199, 1 (2000).

    Article  CAS  Google Scholar 

  21. A.G. Hill, J.H. Shippe, A.J. Hill: Ind. Eng. Chem., 43, 1579 (1951).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Cochin University of Science and Technology Cochin, 682 022, Kerala, India

    Rahna Koyakutty Shamsudeen, Kanat Nisha & Sankaran Sugunan

Authors
  1. Rahna Koyakutty Shamsudeen
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Kanat Nisha
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sankaran Sugunan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Sankaran Sugunan.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Shamsudeen, R.K., Nisha, K. & Sugunan, S. Vanadia impregnated iron-pillared montmorillonite for aniline methylation. Reaction Kinetics and Catalysis Letters 81, 341–348 (2004). https://doi.org/10.1023/B:REAC.0000019442.68117.c8

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:REAC.0000019442.68117.c8

Search

Navigation