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Liquid phase oxidation of n-octane catalyzed by silica gel supported vanadium (VO2+) complex using molecular oxygen

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Abstract

Nitrogen containing Schiff base ligand, [1,2-bis(salicylideneimino)-phenylene] vanadium oxo, has been covalently bonded on chemically modified silica gel support. With this catalyst the oxidation of n-octane with molecular oxygen occurs with chain breaking with very little isomerization.

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Authors and Affiliations

  1. Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur, 208016, INDIA

    Gopal S. Mishra & Anil Kumar

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  1. Gopal S. Mishra
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  2. Anil Kumar
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Mishra, G.S., Kumar, A. Liquid phase oxidation of n-octane catalyzed by silica gel supported vanadium (VO2+) complex using molecular oxygen. Reaction Kinetics and Catalysis Letters 80, 223–231 (2003). https://doi.org/10.1023/B:REAC.0000006129.97554.b6

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  • DOI: https://doi.org/10.1023/B:REAC.0000006129.97554.b6

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