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Phase Formation in Sintering of Materials Based on Silicon Nitride with Li2CO3 and AlN Additives

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Abstract

We have studied the phase formation processes occurring in sintering of materials based on silicon nitride with lithium carbonate and aluminum nitride or Al powder additives. We have studied samples of different compositions that were sintered at 1450, 1550, and 1750°C under a nitrogen atmosphere. We have established that the phase composition depends on the sintering temperature, the composition of the starting charge, and also the amount and the nature of the Al-containing additives.

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REFERENCES

  1. T. S. Bartnitskaya, O. N. Grigor'ev, T. V. Dubovik, et al., “Effect of lithium carbonate on structure formation in ceramic based on Si3 N4,” Poroshk. Metall., Nos. 3-4, 96-101 (2002).

  2. T. S. Bartnitskaya, O. N. Grigor'ev, L. A. Krushinskaya, et al., “Study of phase formation processes in the systems Li–N, Si3 N4–Li3 N, Si3 N 4–Li3 N–Y2 O3,” Poroshk. Metall., Nos. 7–8, 88-92 (2002).

  3. M. V. Mel'nikov, I. I. Raikov, G. V. Samsonov, et al., “Results of comparative tests of electrically insulating materials based on refractory nonmetallic nitrides in lithium vapor at a temperature of 1500°C,” in: Proceedings of TsKBÉM and IPM, Akad. Nauk UkrSSR [in Russian], TsKBÉM, Moscow (1969).

    Google Scholar 

  4. D. N. Poluboyarinov, V. A. Bashtakov, and G. A. Serov, “Tests of highly refractory materials in lithium vapor at high temperatures,” Ogneupory, No. 2, 82-88 (1964).

  5. R. B. Kotel'nikov, S. M. Bashlykov, Z. G. Galiakbarov, et al., Exceptionally Refractory Compounds: Handbook [in Russian], Metallurgiya, Moscow (1969).

    Google Scholar 

  6. M. A. Pilipchuk, I. A. Kedrinskii, S. V. Moroz, et al., “Corrosion resistance of aluminum and silicon nitrides,” in: Refractory Nitrides [in Russian], Nauk. Dumka, Kiev (1983), pp. 118-121.

    Google Scholar 

  7. G. V. Samsonov, T. V. Dubovik, and E. V. Sokhovich, “Resistance of some non-oxygen materials to the action of lithium and barium,” in: Refractory Nitrides [in Russian], Nauk. Dumka, Kiev (1983), pp. 110-112.

    Google Scholar 

  8. H. Yamane, S. Kikkava, and M. Koizumi, “Preparation of lithium silicon nitrides and their lithium ion conductivity,” Solid State Ionics, 25, No. 2-3, 183-191 (1987).

    Google Scholar 

  9. I. T. Beshkarev, Yu. B. Tarakanov, T. V. Dubovik, et al., Electrochemical Cell for Determination of Nitrogen in High-Vacuum Melting, Inventor's Certificate No. 1056035 USSR, Publ. November 23 (1983).

  10. T. Ya. Kosolapova, T. V. Andreeva, T. S. Bartnitskaya, et al., Nonmetallic Refractory Compounds [in Russian], Metallurgiya, Moscow (1985).

    Google Scholar 

  11. Index to the X-Ray Powder Data File, Amer. Soc. Test. Mat., Philadelphia (1985).

  12. A. J. Gordon and R. Ford, Chemist's Companion. A Handbook of Practical Data, Techniques, and References [Russian translation], Mir, Moscow (1976).

    Google Scholar 

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Grigor'ev, O.N., Rogozinskaya, A.A. & Dubovik, T.V. Phase Formation in Sintering of Materials Based on Silicon Nitride with Li2CO3 and AlN Additives. Powder Metallurgy and Metal Ceramics 43, 291–294 (2004). https://doi.org/10.1023/B:PMMC.0000042465.51401.83

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  • DOI: https://doi.org/10.1023/B:PMMC.0000042465.51401.83

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