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Sintering Behavior and Properties of Reaction-Bonded Silicon Nitride

  • Inorganic Chemistry
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Abstract

The influence exerted by the conditions of the preliminary synthesis of Si3N4 by nitridation at 1350 and 1400°С and additional high-temperature sintering at 1800 and 1900°С on the properties of reaction-bonded silicon nitride was studied. Secondary silicon nitride (β-Si3N4) formed in the course of nitridation consists of needle-like grains, which reinforce the material and impart to it additional mechanical strength. The microstructure and phase composition of the silicon nitride material at different initial ratios of silicon and silicon nitride were studied. The materials obtained approach liquid-phase-sintered and hot-pressed silicon nitride in the mechanical properties.

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ACKNOWLEDGMENTS

The equipment was submitted in part by the Engineering Center at the St. Petersburg State Institute of Technology (Technical University).

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Authors and Affiliations

  1. Grebenshchikov Institute of Silicate Chemistry, Russian Academy of Sciences, nab. Makarova 2, 199034, St. Petersburg, Russia

    S. N. Perevislov

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Correspondence to S. N. Perevislov.

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Translated from Zhurnal Prikladnoi Khimii, No. 2, pp. 153–162, January, 2021 https://doi.org/10.31857/S0044461821020031

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Perevislov, S.N. Sintering Behavior and Properties of Reaction-Bonded Silicon Nitride. Russ J Appl Chem 94, 143–151 (2021). https://doi.org/10.1134/S1070427221020038

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