Skip to main content
Log in

Influence of 2 at.% Ruthenium Addition on the Oxidation of γ-TiAl at 900°C in Air

  • Published:
Oxidation of Metals Aims and scope Submit manuscript

Abstract

The structure of oxide scales formed on Ti–55Al and Ti–2Ru–54Al (at. %) by oxidation at 900°C in air was investigated by X-Ray powder diffraction, optical microscopy, scanning-electron microscopy and electron-microprobe analysis. Alloying with ruthenium increases the oxidation resistance during isothermal oxidation, but the opposite trend is observed when samples are oxidized during temperature cycling. This behavior is discussed in terms of the micro-structure of the samples and the oxide scales formed during oxidation.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. T. Izumi, T. Yoshioka, S. Hayashi, and T. Narita, Intermetallics 9, 547 (2001).

    Article  Google Scholar 

  2. J. W. Fergus, Materials Science and Engineering A, 338, 108–125 (2002).

    Article  Google Scholar 

  3. V. Gauthier, F. Dettenwanger, M. Schütze, V. Shemet, and W. J. Quadakkers, Oxidation of Metals 59, 233 (2003).

    Article  Google Scholar 

  4. Y. Shida, and H. Anada, Corrosion Science 35, 945 (1993).

    Article  Google Scholar 

  5. A. Nerac Partaix, and A. Menand, Scripta Materialia 35, 199 (1996).

    Article  Google Scholar 

  6. T. K. Roy, R. Balasubramanian, and A. Ghosh, Metallurgical and Materials Transactions 27A, 3993 (1996).

    Google Scholar 

  7. T. K. Roy, R. Balasubramanian, and A. Ghosh, Metallurgical and Materials Transactions 27A, 4003 (1996).

    Google Scholar 

  8. Y. Shida, and H. Anada, Oxidation of Metals 45, 197 (1996).

    Google Scholar 

  9. M. P. Brady, J. L. Smialek, J. Smith, and D. L. Humphrey, Acta Materialia 45, 2357 (1997).

    Article  Google Scholar 

  10. J. W. Fergus, Oxidation of Metals 48, 201 (1997).

    Google Scholar 

  11. S. A. Kekare, and P. B. Aswath, Journal of Materials Science 32, 2485 (1997).

    Article  Google Scholar 

  12. I. E. Locci, M. P. Brady, R. A. MacKay, and J. W. Smith, Scripta Materialia 37, 761 (1997).

    Article  Google Scholar 

  13. W. J. Quadakkers, N. Zheng, A. Gil, E. Wallura, and H. Hoven, Materials Science Forum 251-254, 187 (1997).

    Google Scholar 

  14. W. J. Quadakkers, P. Schaaf, N. Zheng, A. Gil, and E. Wallura, Materials and Corrosion 48, 28 (1997).

    Google Scholar 

  15. Y. Shida, Y. Kouzuki, and T. Nagata, Journal of the Japan Institute Metals 61, 1365 (1997). 16. F. Dettenwanger, E. Schumann, M. Rühle, J. Rakowski, and G. H. Meier, Oxidation of Metals 50, 269 1998.

    Google Scholar 

  16. M. P. Brady, E. D. Verink Jr, and J. W. Smith, Oxidation of Metals 51, 539 (1999).

    Article  Google Scholar 

  17. N. S. Jacobson, M. P. Brady, and G. M. Mehrotra, Oxidation of Metals 52, 537 (1999).

    Article  Google Scholar 

  18. M. Schmitz-Niederau, and M. Schutze, Oxidation of Metals 52, 225 (1999).

    Article  Google Scholar 

  19. M. Schmitz-Niederau, and M. Schutze, Oxidation of Metals 52, 241 (1999).

    Article  Google Scholar 

  20. M. Yoshihara, and Y. W. Kim, in Gamma Titanium Aluminides-1999, Y.W. Kim, D. M.Dimiduk, and M.H. Loretto eds. (TMS-Minerals Metals and Materials Society San Diego, CA, USA, 1999), pp. 753–760.

    Google Scholar 

  21. F. Dettenwanger, and M. Schutze, Oxidation of Metals 54, 121 (2000).

    Article  Google Scholar 

  22. M. Yoshihara, Y. W. Kim, Journal of the Japan Institute Metals 64, 1020 (2000).

    Google Scholar 

  23. B. Dang, J. W. Fergus, W. F. Gale, and T. Zhou, Oxidation of Metals 56, 15–32 (2001).

    Article  Google Scholar 

  24. S. K. Varma, A. Chan, and R. N. Mahapatra, Oxidation of Metals 55, 423 (2001).

    Article  Google Scholar 

  25. J. C. Woo, S. K. Varma, P. W. Wang, M. Avila, and R. N. Mahapatra, Journal of Materials Science Letters 21, 539 (2002).

    Article  Google Scholar 

  26. M. P. Brady, B. Gleeson, and I. G. Wright, Journal of Metals, 52(1), 16 (2000).

    Google Scholar 

  27. J.J. Ding, H. Schweiger, W. Wolf, P. Rogl, D. Vogtenhuber, and R. Podloucky R. in Gamma Titanium Aluminides-1999, Y.W. Kim, D. M. Dimiduk, and M.H. Loretto eds.(TMS-Miner. Metals and Mater. Soc, San Diego, CA, USA, 1999), pp. 141–147.

    Google Scholar 

  28. P. Huneau, P. Rogl, K. Zeng, R. Schmid-Fetzer, M. Bohn, and J. Bauer, Intermetallics 7, 1337 (1999).

    Article  Google Scholar 

  29. K. Zeng, R. Schmid-Fetzer, B. Huneau, P. Rogl, and J. Bauer, Intermetallics 7, 1347 (1999).

    Article  Google Scholar 

  30. J. J. Ding, P. Rogl, B. Chevalier, and J. Etourneau, Intermetallics 8, 1377 (2000).

    Article  Google Scholar 

  31. J. J. Ding, P. Rogl, H. Schmidt, and R. Podloucky, Visn. Lvivsk, UN-TU. (Visnyk of the Lviv University) Ser. Khim. 39C, 136 (2000).

    Google Scholar 

  32. J. J. Ding, P. Rogl, and H. Schmidt, Journal of Alloys and Compounds 317-318, 379 (2001).

    Article  Google Scholar 

  33. A. Grytsiv, P. Rogl, H. Schmidt, and G. Giester, Journal of Phase Equilibria 24, 511 (2004).

    Article  Google Scholar 

  34. A. Grytsiv, J. J. Ding, P. Rogl, F. Weill, B. Chevalier, J. Etourneau, G. Andrè, F. Bourée, H. Nōel, P. Hundegger, and G. Wiesinger, Intermetallics 11, 351 (2003).

    Article  Google Scholar 

  35. A. Grytsiv, P. Rogl, H. Schmidt, G. Giester, P. Hundegger, G. Wiesinger, and V. Pomjakushin, Intermetallics, 121(5), 563 (2004).

    Article  Google Scholar 

  36. M. Eckert, and K. Hilpert, Materials and Corrosion 48, 10 (1997).

    Google Scholar 

  37. R. Schmid-Fetzer, "A Critical Assessment of the Binary System Al-Ti" in MSIT Binary Evaluation Program, available via MSI workplace, MSIT-product, MSI-Stuttgart, 2002 39. T. Roisnel, and J. Rodriguez-Carvajal, Materials Science Forum 378-381, 118 (2001).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to P. Rogl.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Grytsiv, A., Rogl, P. & Schmidt, H. Influence of 2 at.% Ruthenium Addition on the Oxidation of γ-TiAl at 900°C in Air. Oxidation of Metals 62, 15–28 (2004). https://doi.org/10.1023/B:OXID.0000038783.02712.a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:OXID.0000038783.02712.a0

Navigation