Abstract
The mechanism of formation of the diffusion layer due to vacuum carburizing of complexly alloyed steel 16Kh3NVFMB-Sh (VKS5) in a medium of acetylene is considered. It is shown that the process of carburizing occurs in a self-regulation mode without the danger of carbon black due to the high rate of arrival of carbon from the gas medium as a result of catalytic dissociation of acetylene molecules, intense process of carbide formation on the saturated surface, and absence of catalytic activity of carbides. The diffusion layer forms under a thin layer of the carbide phase in a kinetic regime, the intensity of which is determined by the rate of dissolution of carbides.
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Ryzhov, N.M., Smirnov, A.E., Fakhurtdinov, R.S. et al. Special Features of Vacuum Carburizing of Heat-Resistant Steel in Acetylene. Metal Science and Heat Treatment 46, 230–235 (2004). https://doi.org/10.1023/B:MSAT.0000043108.71523.08
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DOI: https://doi.org/10.1023/B:MSAT.0000043108.71523.08