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Estimation of Enthalpies of Alkoxy Radical Formation and Bond Strengths in Alcohols and Ether

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Abstract

Kinetic data on the thermal decomposition of peroxides were analyzed, and energies of the O–O bond dissociation were calculated. Enthalpies of formation of various alkoxy radicals and peroxides were determined. The dissociation energies for the O–H bonds in alcohols and C–O bonds in ethers were estimated. Comparative analysis of literature and obtained data was performed.

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  1. Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Russia

    V. E. Tumanov & E. T. Denisov

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  1. V. E. Tumanov
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  2. E. T. Denisov
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Tumanov, V.E., Denisov, E.T. Estimation of Enthalpies of Alkoxy Radical Formation and Bond Strengths in Alcohols and Ether. Kinetics and Catalysis 45, 621–627 (2004). https://doi.org/10.1023/B:KICA.0000044971.14314.36

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