Skip to main content
Log in

TG-MS as a technique for a better monitoring of the pyrolysis, gasification and combustion of two kinds of sewage sludge

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

Sewage sludge disposal is a difficult task owing to increasingly restrictive re-use policies. Its final destination will obviously depend on its nature and composition but the generation of energy is a significant option. The thermochemical conversion requires exhaustive gas emission controls. In this regard, this paper offers the results of the use of mass spectrometry together with a thermogravimetric analysis system used to study the thermal conversion processes of two kinds of sewage sludge under different atmospheres simulating pyrolysis, gasification and combustion. This TG-MS combination indicates that gasification is the best process for one kind of sludge while a co-combustion process is more suitable for the other.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Renner 2000; European Environment Agency Indicator Fact Sheet Signals 2001-Chapter Waste.

  2. J. Werther and T. Ogada, Prog. Energy Combus. Sci., 25 (1999)55.

    Article  CAS  Google Scholar 

  3. M. Otero, L. F. Calvo, B. Estrada, A. I. García and A. Morán, Thermochim. Acta, 389 (2002)121.

    Article  CAS  Google Scholar 

  4. J. Rodríguez-Añón, J. Proupin, M. González-Añón and L. Núñez-Regueira, J. Therm. Anal. Cal., 52 (1998)1005.

    Article  Google Scholar 

  5. P. J. Matthews, European progress on the political and economic concerns of sludge disposal-is the future biosolids or ash? In: Proceedings of the EWPCA-NVA Conference on Future of Water Quality Management in Europe, Aquatech, Amsterdam, September,1996

  6. L. F. Calvo, M. Otero, B. M. Jenkins, A. I. García and A. Morán, Thermochim. Acta, 409 (2004)127.

    Article  CAS  Google Scholar 

  7. C. Díez, O. Martínez, L. F. Calvo, J. Cara and A. Morán, Waste Management, 24 (2004)463.

    Article  Google Scholar 

  8. A. Napoli, Ph.D. Thesis, Université Paul Sabatier de Toulouse, France1998.

  9. B. Pacewska, A. Klepariska, P. Stefaniak and D. Szychowski, J. Therm. Anal. Cal., 60 (2000)229.

    Article  CAS  Google Scholar 

  10. J. Heikinen and H. Spliethoff, J. Therm. Anal. Cal., 72 (2003)1031.

    Article  Google Scholar 

  11. J. H. Ferrase, S. Chávez, P. Arlabosse and N. Dupuy, Thermochim. Acta, 404 (2003)97.

    Article  Google Scholar 

  12. A. Arenillas, F. Rubiera and J. J. Pis, J. Anal. Appl. Pyrolysis, 50 (1999)31.

    Article  CAS  Google Scholar 

  13. M. C. M. Alvim-Ferraz and S. A. V. Afonso, Atmos. Environ., 37 (2003)5415.

    Article  CAS  Google Scholar 

  14. V. I. Kouprianov and W. Permchart, Appl. Energy, 74 (2003)383.

    Article  CAS  Google Scholar 

  15. A. M. Henihan, M. J. Leahy, J. J. Leahy, E. Cummins and B. P. Lelleher, Bioresource Technol., 87 (2003)289.

    Article  CAS  Google Scholar 

  16. H. Liu and B. M. Gibbs, Fuel, 82 (2003)1591.

    CAS  Google Scholar 

  17. C. Díez, O. Martínez, L. F. Calvo, J. Cara and A. Morán, Waste Management, 24 (2004)463.

    Article  Google Scholar 

  18. L. Zhang, A. Sato, Y. Ninomiya and E. Sasaoka, Fuel, 83 (2004)1039.

    Article  CAS  Google Scholar 

  19. P. J. Hatton and B. W. Southward, J. Therm. Anal. Cal., 72 (2003)83.

    Article  CAS  Google Scholar 

  20. A. Arenillas, F. Rubiera and J. J. Pis, J. Anal. Appl. Pyrolysis, 50 (1999)31.

    Article  CAS  Google Scholar 

  21. J. Werther and T. Ogada, Prog. Energy Combust. Sci., 25 (1999)55.

    Article  CAS  Google Scholar 

  22. M. Otero, L. F. Calvo, B. Estrada, A. I. García and A. Morán, Thermochim. Acta, 389 (2002)121.

    Article  CAS  Google Scholar 

  23. M. Otero, L. F. Calvo, B. Estrada, A. I. García and A. Morán, Thermochim. Acta, 389 (2002)121.

    Article  CAS  Google Scholar 

  24. A. B. Singh, Ph.D. Thesis, University of California, Davis1996.

  25. J. T. Shaw, J. Inst. Fuel, 64 (1973)170.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Calvo, L.F., Sánchez, M.E., Morán, A. et al. TG-MS as a technique for a better monitoring of the pyrolysis, gasification and combustion of two kinds of sewage sludge. Journal of Thermal Analysis and Calorimetry 78, 587–598 (2004). https://doi.org/10.1023/B:JTAN.0000046121.14253.38

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JTAN.0000046121.14253.38

Navigation