Abstract
Ho(III), Er(III) and Yb(III) complexes of 2-hydroxy-1,4-naphthoquinone-1-oxime derivatives having [ML3(H2O)2] are characterized using spectral and thermal decomposition studies. The thermolytic patterns suggested that they are decomposed in three distinct stages; 1ststage is related to the loss of two coordinated water molecules while one of the coordinated ligands and remaining two ligands are lost during subsequent 2nd and 3rd stages of degradation. After the 2nd stage, the structure of these complexes is reorganized reflecting that the structural associations through intermolecular hydrogen bonding network is essential for thermal stability. The kinetic parameters computed for 2nd step using the non-isothermal procedures of Coats-Redfern are applied to the respective differential thermogravimetric plots to ascertain the thermal degradation mechanism in air. The order of thermal decomposition reaction is found to be between 1-2 indicating that more than one intermediate might have simultaneously been formed. It also reveals the intermixing of 1st and 3rd stages of decomposition with the predominant 2nd stage leading to more gradual degradation. Energy of activation for 2nd stage of decomposition for these complexes is comparatively lower than those observed earlier for similar types of complexes. Other spectral data indicate oximino nitrogen and phenolato oxygen as coordination sites of 2-hydroxy-1,4-naphthoquinone monoximates.
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Jagtap, S.B., Chikate, R.C., Yemul, O.S. et al. Thermal, spectral and magnetic properties of 2-hydroxy-1,4-naphthoquinone monoximates of Ho(III), Er(III) and Yb(III). Journal of Thermal Analysis and Calorimetry 78, 251–262 (2004). https://doi.org/10.1023/B:JTAN.0000042172.51676.7f
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DOI: https://doi.org/10.1023/B:JTAN.0000042172.51676.7f