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Studies of phase equilibria in the systems ZnCl2-AgCl and ZnBr2-AgBr

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Abstract

Phase equilibria in the systems zinc chloride - silver chloride and zinc bromide - silver bromide were investigated by differential scanning calorimetry, electric conductivity measurements and X-ray diffraction methods. No intermediate compounds were found. Solubility of components in the solid-state is negligible. Both systems are of the eutectic type. The eutectic temperatures in the ZnCl2-AgCl system and in the ZnBr2-AgBr system are 504 K and 551 K, respectively, and the compositions of the eutectic point are 53.5 mol% AgCl and 59.4 mol% AgBr, respectively.

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Authors and Affiliations

  1. Laboratory of Thermal Analysis, Department of Inorganic Chemistry, Faculty of Pharmacy, Wrocław Medical University ul, Szewska 38, 50139, Wrocław, Poland

    Alina Wojakowska, Agata Górniak & Stanisława Plińska

  2. The W.Trzebiatowski Institute of Low Temperature and Structure Research, Polish Academy of Sciences Okólna 2, 50 950, Wrocław 2, Poland

    A. Wojakowski

Authors
  1. Alina Wojakowska
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  2. Agata Górniak
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  3. A. Wojakowski
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  4. Stanisława Plińska
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Correspondence to Alina Wojakowska.

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Wojakowska, A., Górniak, A., Wojakowski, A. et al. Studies of phase equilibria in the systems ZnCl2-AgCl and ZnBr2-AgBr. Journal of Thermal Analysis and Calorimetry 77, 41–47 (2004). https://doi.org/10.1023/B:JTAN.0000033186.52150.8d

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  • DOI: https://doi.org/10.1023/B:JTAN.0000033186.52150.8d

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