Skip to main content
SpringerLink
Log in

Mechanism and kinetics of thermal decomposition of nickel(II) sulfate(VI) hexahydrate

  • Published:
Journal of Thermal Analysis and Calorimetry Aims and scope Submit manuscript

Abstract

This work presents results of research on thermal decomposition of nickel(II) sulfate(VI) hexahydrate in air and in helium atmosphere. On the base of TG and XRD results a mechanism of thermal decomposition of NiSO4 hydrate was established. For calculations of kinetic parameters of the Arrhenius equation, the Coats-Redfern approximation was applied. Choice of g(a) function and thus of a mechanism best describing given stage of decomposition was performed by testing 12 kinetic models.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. J. R. Sohn and D. C. Shin, J. Catal., 160 (1996) 314.

    Article  CAS  Google Scholar 

  2. J. R. Sohn, H. W. Kim, M. Y. Park, E. H. Park, J. T. Kim and S. E. Park, Appl. Catal. A: Gen., 128 (1995) 127.

    Article  CAS  Google Scholar 

  3. J. R. Sohn and S. Y. Lee, Appl. Catal. A: Gen., 164 (1997) 127.

    Article  CAS  Google Scholar 

  4. J. R. Sohn and W. C. Park, Appl. Catal. A: Gen., 239 (2003) 269.

    Article  CAS  Google Scholar 

  5. J. E. Funk and R. M. Reinstrom, Ind. Eng. Chem. Process Des. Dev., 5 (1966) 336.

    Article  CAS  Google Scholar 

  6. A. W. Coats and I. P. Redfern, Nature, 201 (1964) 68.

    Article  CAS  Google Scholar 

  7. H. Tagawa and H. Saijo, Thermochim. Acta, 91 (1985) 67.

    Article  CAS  Google Scholar 

  8. H. Tagawa, Thermochim. Acta, 80 (1984) 23.

    Article  CAS  Google Scholar 

  9. G. A. Kolta and M. H. Askar, Thermochim. Acta, 11 (1975) 65.

    Article  CAS  Google Scholar 

  10. R. V. Siriwardane, J. A. Poston, E. P. Fisher, M. S. Shen and A. L. Miltz, Appl. Surf. Sci., 152 (1999) 219.

    Article  CAS  Google Scholar 

  11. JCPDF PDF No: 77–0682, 17–0483, 81–0021.

  12. M. E. Brown, D. Dollimore and A. K. Galwey, Reactions in the Solid State, Comprehensive Chemical Kinetics, Vol. 22, Elsevier, Amsterdam 1980.

    Google Scholar 

  13. E. Ingier-Stocka, J. Therm. Anal. Cal., 65 (2001) 561.

    Article  CAS  Google Scholar 

  14. V. Jordanovska, B. Boyanow and Lj. Pejov, J. Therm. Anal. Cal., 71 (2003) 629.

    Article  CAS  Google Scholar 

  15. V. Petkova and Y. Pelovski, J. Therm. Anal. Cal., 64 (2001) 1037.

    Article  CAS  Google Scholar 

  16. V. Petkova and Y. Pelovski, J. Therm. Anal. Cal., 64 (2001) 1025.

    Article  CAS  Google Scholar 

  17. Y. Pelovski, V. Petkova and S. Nikolov, Thermochim. Acta, 274 (1996) 273.

    Article  CAS  Google Scholar 

  18. V. Jordanovska, B. Boyanow and Lj. Pejov, J. Therm. Anal. Cal., 71 (2003) 629.

    Article  CAS  Google Scholar 

  19. B. V. L'vov and V. L. Ugolkov, J. Therm. Anal. Cal., 74 (2003) 583.

    Article  Google Scholar 

  20. E. Tomaszewicz and M. Kotfica, J. Therm. Anal. Cal., 74 (2003) 583.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry and Environment Protection al. Piastów 42, Technical University of Szczecin, 71-065, Szczecin, Poland

    E. Tomaszewicz & M. Kotfica

Authors
  1. E. Tomaszewicz
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Kotfica
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tomaszewicz, E., Kotfica, M. Mechanism and kinetics of thermal decomposition of nickel(II) sulfate(VI) hexahydrate. Journal of Thermal Analysis and Calorimetry 77, 25–31 (2004). https://doi.org/10.1023/B:JTAN.0000033184.32714.7f

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JTAN.0000033184.32714.7f

Search

Navigation