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Neodymium and europium complexes with amides and cyclic aminoxides

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Abstract

Complexes of neodymium and europium with amides and aminoxides were synthesized and characterized by complexometric analyses with EDTA, CHN microanalytical procedures, IR absorption spectra, absorption spectra of neodymium complexes, emission spectrum of europium compounds at 77 K, thermogravimetric analyses in N2 and differential scanning calorimetry (DSC) in N2. Infrared spectroscopy results revealed that the nitrate molecules are bound to the central ions as bidentate. Thermogravimetric plots indicated that the decomposition of the complexes occurs in the range 363-1163 K and resulted in the formation of Ln2O3 residues.

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Authors and Affiliations

  1. Departamento de Química, Universidade Federal do Rio Grande do Norte, C. P. 1662, 59078-970, Natal, RN, Brazil E-mail

    D. M. A Melo, K. Zinner, H. K. S. de Souza, M. K. S Batista, A. M. Garrido Pedrosa & R. F. Bezerra

  2. Instituto de Química, Universidade de Săo Paulo, C. P. 26077, 05513-970, Săo Paulo, SP, Brazil

    G. Vicentini & L. B. Zinner

Authors
  1. D. M. A Melo
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  2. G. Vicentini
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  3. L. B. Zinner
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  4. K. Zinner
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  5. H. K. S. de Souza
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  6. M. K. S Batista
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  7. A. M. Garrido Pedrosa
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  8. R. F. Bezerra
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Correspondence to D. M. A Melo.

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Melo, D.M.A., Vicentini, G., Zinner, L.B. et al. Neodymium and europium complexes with amides and cyclic aminoxides. Journal of Thermal Analysis and Calorimetry 75, 623–628 (2004). https://doi.org/10.1023/B:JTAN.0000027154.27766.2c

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  • DOI: https://doi.org/10.1023/B:JTAN.0000027154.27766.2c

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