Skip to main content
Log in

Uptake of radionuclides on antimony silicate

  • Published:
Journal of Radioanalytical and Nuclear Chemistry Aims and scope Submit manuscript

Abstract

The uptake of fission products 137Cs, 85Sr, 57Co, onto an antimony silicate, and its Na, K, Ca ion-exchanged forms have been studied. Distribution coefficients have been determined as a function of the concentrations of sodium, potassium and calcium nitrate solutions (0.01, 0.1 and 1M). Plots of log distribution coefficients against concentrations enabled the elucidation of exchange mechanisms in some cases. Potassium had the least, and calcium the most effect on isotope uptake when present as macro ions. The presence of sodium promoted hydrolysis that also affected the exchange selectivity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. Y. Koudsi, A. Dyer, J. Radioanal. Nucl. Chem., 247 (2001) 209.

    Article  CAS  Google Scholar 

  2. L. Al-Attar, A. Dyer, R. Harjula, J. Mater. Chem., submitted.

  3. L. Al-Attar, A. Dyer, R. Harjula, A. Paajanen, J. Mater. Chem., submitted.

  4. R. Harjula, A. Dyer, S. D. Pearson, R. P. Townsend, J. Chem. Soc., Faraday Trans., 89 (1993) 1491.

    Google Scholar 

  5. M. Abe, in: Inorganic Ion Exchange Materials, A. Clearfield (Ed.), CRC Press, Boca Raton, Florida, 1982, p. 197.

    Google Scholar 

  6. W. A. England, M. G. Cross, A. Hamnett, P. J. Wiseman, J. B. Goodenough, Solid State Ionics, (1982) 231.

  7. K. G. Varshney, U. Sharma, S. Rani, A. Premadas, Separ. Sci. Technol., 17 (1982–1983) 1527.

    Article  CAS  Google Scholar 

  8. T. MÖller, R. Harjula, M. Pillinger, A. Dyer, J. Newton, E. Tusa, S. Amin, M. Webb, A. Araya, J. Mater. Chem., 11 (2000) 1526.

    Article  Google Scholar 

  9. T. MÖller, A. Clearfield, R. Harjula, Chem. Mater., 13 (2001) 4767.

    Article  CAS  Google Scholar 

  10. A. Dyer, M. Pillinger, J. Newton, R. Harjula, T. MÖller, S. Amin, Chem. Mater., 13 (2001) 4767.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

About this article

Cite this article

Al-Attar, L., Dyer, A. & Harjula, R. Uptake of radionuclides on antimony silicate. Journal of Radioanalytical and Nuclear Chemistry 260, 199–203 (2004). https://doi.org/10.1023/B:JRNC.0000027081.13815.b4

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JRNC.0000027081.13815.b4

Keywords

Navigation