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Crystal Structure Investigation of Ternary Potassium–Manganese–Zirconium Molybdate with a Nasicon Type Structure

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Abstract

The crystal structure and composition of the ternary (K, Mn, Zr) molybdate were refined using X-ray diffraction data (KM-4 KUMA-Diffraction automatic diffractometer, MoKα radiation, graphite monochromator, ω scan mode, 548 F(hkl), R=0.0427). The unit cell dimensions are a=b=9.474(1), c=24.371(4) Å, V=1894.4 Å3, Z=6, Ρcalc = 3.337 g/cm3, space group R\(\bar 3\)c. The crystal structure is a 3D framework of oxygen vertex-sharing (Mn, Zr)O6 octahedra and MoO4 tetrahedra, with potassium atoms located in the large channels; it belongs to the Nasicon structural type.

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REFERENCES

  1. Zh. G. Bazarova, B. G. Bazarov, R. F. Klevtsova, et al., Zh. Strukt. Khim., 35 No.6, 1007-1009 (1994).

    Google Scholar 

  2. R. F. Klevtsova, Zh. G. Bazarova, L. A. Glinskaya, et al., ibid., 35 No.3, 11-15 (1994).

    Google Scholar 

  3. R. F. Klevtsova, Zh. G. Bazarova, L. A. Glinskaya, et al., ibid., 36 No.5, 891-894 (1995).

    Google Scholar 

  4. R. F. Klevtsova, Zh. G. Bazarova, L. A. Glinskaya, et al., ibid., 895-899.

  5. G. M. Sheldrick, SHELX-97, Release 97-2, Univ. Göttingen, Germany (1998).

    Google Scholar 

  6. L. O. Hagman and P. Kierkegaard, Acta Chem. Scand., 22 No.6, 1822-1832 (1968).

    Google Scholar 

  7. H. Y.-P. Hong, Mat. Res. Bull., 11, 173-182 (1976).

    Google Scholar 

  8. A. K. Ivanov-Shitz, A. B. Bykov, and I. A. Verin, Kristallografiya, 41 No.6, 1060-1062 (1996).

    Google Scholar 

  9. H. Kohler and H. Schulz, Mat. Res. Bull., 21 No.1, 23-31 (1986).

    Google Scholar 

  10. A. Leclaire, M. M. Borel, A. Grandin, and B. Raveau, ibid., 26 No.2, 207-211.

  11. B. I. Lazoryak and V. A. Efremov, Zh. Neorg. Khim., 32 No.3, 652-656 (1987).

    Google Scholar 

  12. Z. I. Khazheeva, V. I. Simonov, M. V. Mokhosoev, et al., Kristallografiya, 32 No.1, 79-82 (1987).

    Google Scholar 

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Russia

    R. F. Klevtsova, L. A. Glinskaya & P. V. Klevtsov

  2. Baikal Institute of Natural Resources Utilization, Siberian Branch, Russian Academy of Sciences, Ulan-Ude

    B. G. Bazarov & Zh. G. Bazarova

  3. L. V. Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk

    A. D. Vasiliev

Authors
  1. R. F. Klevtsova
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  2. B. G. Bazarov
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  3. L. A. Glinskaya
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  4. A. D. Vasiliev
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  5. P. V. Klevtsov
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  6. Zh. G. Bazarova
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Klevtsova, R.F., Bazarov, B.G., Glinskaya, L.A. et al. Crystal Structure Investigation of Ternary Potassium–Manganese–Zirconium Molybdate with a Nasicon Type Structure. Journal of Structural Chemistry 44, 893–896 (2003). https://doi.org/10.1023/B:JORY.0000029833.70180.d8

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  • DOI: https://doi.org/10.1023/B:JORY.0000029833.70180.d8

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