Skip to main content
SpringerLink
Log in

Synthesis, Structure, and Reversible Thermochromism of Guanidinium Hexabromotellurate(IV)

  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Guanidinium hexabromotellurate(IV), C2H12N6TeBr6, has been synthesized and characterized by element analysis and diffuse reflectance spectroscopy. Its crystal structure has been determined (R=0.027). The complex is built from layers of [TeBr6]2− anions and [CH5N3H]+ cations linked by N–H...Br hydrogen bonds and united by van der Waals interactions into a 3D framework. The electronic factors governing the spectral behavior of the complexes at 100 and 300 K are discussed, and reversible thermochromism has been revealed.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. D. J. Stufkens, Rec. Trav. Chim., 89 No.11, 1185-1201 (1970).

    Google Scholar 

  2. D. J. Stufkens and A. Schenk, ibid., 90, 190-192 (1971).

    Google Scholar 

  3. D. A. Couch, C. J. Wilkins, G. R. Rossman, and H. B. Gray, J. Am. Chem. Soc., 92 No.2, 307-310 (1970).

    Google Scholar 

  4. A. Vogler and A. Paukner, J. Photochem. Photobiol. A, 46, 227-231 (1989).

    Google Scholar 

  5. P. J. H. Drummen, H. Donker, W. M. A. Smit, and G. Blasse, Chem. Phys. Lett., 144 Nos.5/6, 460-462 (1988).

    Google Scholar 

  6. A. G. Mirochnik, N. V. Petrochenkova, V. E. Karasev, et al., Rec. Trav. Chim., 27 No.11, 831-833 (2001).

    Google Scholar 

  7. T. V. Storozhuk, A. A. Udovenko, A. G. Mirochnik, et al., ibid., 28 No.3, 185-192 (2002).

    Google Scholar 

  8. A. K. Babko and I. V. Pyatnitskii, Quantitative Analysis [in Russian], Gos. Nauch. Tekh. Izd. Khim. Lit., Moscow (1956).

    Google Scholar 

  9. SMART and SAINT-Plus, Versions 5. 0, Data Collection and Processing Software for the SMART System, Bruker AXS Inc., Madison, WI (1998).

  10. G. M. Sheldrick, SHELXTL/PC, Versions 5. 0, An Integrated System for Solving, Refining, and Displaying Crystal Structures from Diffraction Data, Bruker AXS Inc., Madison, WI (1998).

    Google Scholar 

  11. E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, J. Phys. C:Solid State Phys., 19, 3263-3272 (1986).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute of Chemistry, Far East Branch, Russian Academy of Sciences, Vladivostok

    T. V. Storozhuk, B. V. Bukvetskii, A. G. Mirochnik & V. E. Karasev

Authors
  1. T. V. Storozhuk
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. V. Bukvetskii
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. G. Mirochnik
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. V. E. Karasev
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Storozhuk, T.V., Bukvetskii, B.V., Mirochnik, A.G. et al. Synthesis, Structure, and Reversible Thermochromism of Guanidinium Hexabromotellurate(IV). Journal of Structural Chemistry 44, 880–884 (2003). https://doi.org/10.1023/B:JORY.0000029830.73340.3b

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JORY.0000029830.73340.3b

Search

Navigation