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Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS -2 , C4H8NCS -2 ; A = NH +4 , Et4N+)

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Abstract

Complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS -2 , C4H8NCS -2 ; A = NH +4 , Et4N+) are synthesized. The crystal structure of compound [Gd(Phen)(iso-Bu2PS2)3] · MeCN is determined by X-ray diffraction analysis (CIF file CCDC no. 1455418). The structure consists of molecules of the mononuclear complex [Gd(Phen)(iso-Bu2PS2)3] and MeCN. The coordination polyhedron N2S6 of the Gd atom is a distorted antiprism. The complexes exhibit phosphorescence in a range of 400–600 nm. The energies of the triplet levels of the ligands C4H8NCS -2 (23336 cm–1) and iso-Bu2PS -2 (23506 cm–1) are determined from the phosphorescence spectra of complexes (A)[Gd(L)4] in frozen ethanol (77 K).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, pr. akademika Lavrent’eva 3, Novosibirsk, 630090, Russia

    Yu. A. Bryleva, L. A. Glinskaya, I. V. Korol’kov, D. A. Piryazev & S. V. Larionov

  2. Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russia

    V. F. Plyusnin, I. V. Korol’kov, D. A. Piryazev & S. V. Larionov

  3. Voevodsky Institute of Chemical Kinetics and Combustion, Siberian Branch, Russian Academy of Sciences, Institutskaya ul. 3, Novosibirsk, 630090, Russia

    V. F. Plyusnin & A. S. Kupryakov

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  1. Yu. A. Bryleva
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  2. V. F. Plyusnin
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  3. L. A. Glinskaya
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  4. A. S. Kupryakov
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  5. I. V. Korol’kov
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  6. D. A. Piryazev
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  7. S. V. Larionov
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Correspondence to Yu. A. Bryleva.

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Original Russian Text © Yu.A. Bryleva, V.F. Plyusnin, L.A. Glinskaya, A.S. Kupryakov, I.V. Korol’kov, D.A. Piryazev, S.V. Larionov, 2017, published in Koordinatsionnaya Khimiya, 2017, Vol. 43, No. 3, pp. 138–146.

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Bryleva, Y.A., Plyusnin, V.F., Glinskaya, L.A. et al. Syntheses, structures, and phosphorescence of complexes (A)[Gd(L)4] and [Gd(Phen)(L)3] (L = iso-Bu2PS -2 , C4H8NCS -2 ; A = NH +4 , Et4N+). Russ J Coord Chem 43, 147–155 (2017). https://doi.org/10.1134/S1070328417020026

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