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Size-Resolved Aerosol Characterization for a Polluted Episode at the IfT Research Station Melpitz in Autumn 1997

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Abstract

Inorganic ions, organic carbon (OC), elemental carbon (EC) and a variety of organic single species in airborne particles have been determined at the research station of the Leibniz – Institut für Troposphärenforschung (IfT) in Melpitz (Germany) in autumn 1997.

Samples of eight selected measurement events were divided in two groups in order to investigate differences in the chemical composition of particles originating from southwesterly (SW – developed EU countries) or from easterly directions (E – less developed eastern countries). Differences between these two groups were tested statistically by Student's t-test.

Five stage cascade impactor samples show nitrate as most abundant in the accumulation mode in the SW group. EC and sulphate show the most abundant mass fractions in the E group. That can be considered as a consequence of domestic coal heating and coal-fired power plant emissions in the region of westerly Poland, northern Czech Republic and easterly Germany. Higher nitrate concentrations in the SW group can be explained by stronger NO x emissions caused by the leeward plume of the conurbation of Leipzig, as well as by the still higher traffic density in western Germany.

The methane sulphonic acid (MSA) mass fraction was higher for SW air masses in accumulation mode particles, probably indicating marine origin. Succinic acid also showed higher mass fractions for the SW group. This could be caused by primary emission in automobile exhaust gases and photochemical formation during transport from SW. Indeed, during SW sampling, solar radiation intensity was higher than during E sampling.

The observed differences in the particle composition are an expression of the still existing technology gradient in Europe. Future campaigns could show the development to a joint economy with smaller differences in anthropogenic emissions.

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References

  • Allen, O. J., Dookeran, N. M., Smith, K. A., Sarofim, A. F., Tagizadeh, K., and Lafleur, A. L., 1996: Measurement of polycyclic aromatic hydrocarbons associated with size-segregated atmospheric aerosols in Massachusetts, Environ. Sci. Technol. 30, 1023–1031.

    Google Scholar 

  • Bardouki, H., Liakakou, H., Economou, C., Sciare, J., Smolik, J., ? Zdimal, V., Eleftheriadis, K., Lazaridis, M., Dye, C., and Mihalopoulos, N., 2003: Chemical composition of size-resolved atmospheric aerosols in the eastern Mediterranean during summer and winter, Atmos. Environ. 37, 195–208.

    Google Scholar 

  • Bates, T. S., Huebert, B. J., Gras, J. L., Griffith, F. B., and Durkee, P. A., 1998: International Global Atmospheric Chemistry (IGAC) project's first aerosol experiment (ACE 2): Overview, J. Geophys. Res. 103, 16297–16318.

    Google Scholar 

  • Berresheim, H. J., Huey, W., Thorn, R. P., Eisele, F. L., Tanner, D. J., and Jefferson, A., 1998: Measurements of dimethyl sulfide, dimethyl sulfoxide, dimethyl sulfone and aerosol ions at Palmer station, Antarctica, J. Geophys. Res. 103, 1629–1637.

    Google Scholar 

  • Brüggemann, E. and Rolle,W., 1998: Changes of some components of precipitation in East Germany after the unification, Water, Air Soil Poll. 107, 1–23.

    Google Scholar 

  • Brüggemann, E. and Spindler, G., 1999:Wet and dry deposition of sulphur at the site Melpitz in East Germany, Water, Air Soil Poll. 109, 81–99.

    Google Scholar 

  • Cadle, S. H. and Mulawa, P. A., 1990: Atmospheric carbonaceous species measurement methods comparison study: General Motors results, Aer. Sci. Technol. 12, 128–141.

    Google Scholar 

  • Castro, L. M., Pio, C. A., Harrison, M., and Smith, D. J. T., 1999: Carbonaceous aerosol in urban and rural European atmospheres: estimation of secondary organic carbon concentrations, Atmos. Environ. 33, 2771–2781.

    Google Scholar 

  • Charlson, R. J., Lovelock, J. E., Andreae, M. O., and Warren, S. G., 1987: Oceanic phytoplankton, atmospheric sulfur, cloud albedo and climate, Nature 326, 655–661.

    Google Scholar 

  • Countess, R. J., 1990: Interlaboratory analyses of carbonaceous aerosol samples, Aer. Sci. Technol. 12, 114–121.

    Google Scholar 

  • Friedrich, R., 1996: Ermittlung von Luftschadstoffemissionen in den neuen Bundesländern. Wissenschaftliches Begleitprogramm zur Sanierung der Atmosphäre über den neuen Bundesländern (SANA). Subprojekt A 1.2. Band 1, SANA-Abschlussbericht Nov. 1996, IFU Garmisch-Partenkirchen. 154 A. PLEWKA ET AL.

  • Gelencser, A., Barcza, T., Kiss, G., Molnar, A., Hlavay, J., and Meszaros, E., 1998: Distribution of n-alkanes and PAHs in atmospheric aerosols, Atmos. Res. 46, 223–231.

    Google Scholar 

  • Gray, H. A., Cass, G. R., Huntzicker, J. J., Heyerdahl, E. K., and Rau, J. A., 1986: Characteristics of atmospheric organic carbon and its elemental carbon particle concentration in Los Angeles, Environ. Sci. Technol. 20, 580–589.

    Google Scholar 

  • Gray, H. A. and Cass, G. R., 1998: Source contributions to atmospheric fine particle concentrations, Atmos. Environ. 32, 3805–3825.

    Google Scholar 

  • Harrison, R. M., Smith, J. T., and Luhana, L., 1996: Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban Location in Birmingham, U.K., Environ. Sci. Technol. 30, 825–832.

    Google Scholar 

  • Heintzenberg, J., 1989: Fine particles in the global troposphere: A review, Tellus 41B, 149–160.

    Google Scholar 

  • Herrmann, H., Brüggemann, E., Franck, U., Gnauk, T., Müller, K., Neusüß, C., Plewka, A., Spindler, G., Stärk, H.-J., and Wennrich, R., 2000: Korngrößendifferenzierte Identifikation der Anteile verschiedener Quellgruppen an der Feinstaubbelastung, Abschlussbericht für das Sächsische Landesamt für Umwelt und Geologie (13–8802.3521/46).

  • Kawamura, K. and Kaplan, I. R., 1987: Motor exhaust emissions as a primary source for dicarboxylic acids in Los Angeles ambient air, Environ. Sci. Technol. 21, 105–110.

    Google Scholar 

  • Kawamura, K. and Ikushima, K., 1993: Seasonal changes in the distribution of dicarboxylic acids in the urban atmosphere, Environ. Sci. Technol. 27, 2227–2235.

    Google Scholar 

  • Kleemann, M. J., Schauer, J. J., and Cass, G. R., 2000: Size and composition distribution of fine particulate matter emitted from motor vehicles, Environ. Sci. Technol. 34, 1132–1142.

    Google Scholar 

  • Limbeck, A. and Puxbaum, H., 1999: Organic acids in continental background aerosols, Atmos. Environ. 33, 1847–1852.

    Google Scholar 

  • Maenhaut, W., Cafmeyer, J., Dubtsov, S., and Chi, X., 2002: Detailed mass size distribution of elements and species, and aerosol chemical mass closure during fall 1999 at Gent, Belgium, Nucl. Instrum. Methods 189, 238–242

    Google Scholar 

  • Marquardt, W., Brüggemann, E., Auel, R., Herrmann, H., and Möller, D., 2001: Trends of pollution in rain over East Germany caused by changing emissions, Tellus 53B, 529–545.

    Google Scholar 

  • Mehlmann, A., 1986: Größenverteilung des Aerosolnitrates und seine Beziehung zur gasförmigen Salpetersäure, Dissertation Universität Mainz.

  • Mészáros, E., Barcza, A., Gelencsér, A., Hlavay, J., Kiss, G., Kriváscy, Z., Molnár, A., and Polyák, K., 1997: Size distribution of inorganic and organic species in the atmospheric aerosol, J. Aerosol Sci. 28, 1163–1175.

    Google Scholar 

  • Mészáros, E., Molnár, A., and Ogren, J., 1998: Scattering and absorption coefficients vs. chemical composition of fine atmospheric aerosol particles under regional conditions in Hungary, J. Aerosol Sci. 29, 1171–1178.

    Google Scholar 

  • Müller, K., 1999: A 3 year study of the aerosol in northwest Saxony (Germany), Atmos. Environ. 33, 1679–1685.

    Google Scholar 

  • Neusüß, C., 2000: Größenaufgelöste Zusammensetzung atmosphärischer Aerosolpartikel: Chemische Massenbilanz und organische Säuren, Dissertation Universität Leipzig.

  • Neusüß, C., Pelzing, M., Plewka, A., and Herrmann, H., 2000: A new analytical approach for size resolved speciation of organic compounds in atmospheric aerosol particles: Methods and first results, J. Geophys. Res. 105, 4513–4527.

    Google Scholar 

  • Neusüß, C., Gnauk, T., Plewka, A., Herrmann, H., and Quinn, P. K., 2002a: Carbonaceous aerosol over the Indian Ocean: OC/EC fractions and selected specifications from size-segregated onboard samples, J. Geophys. Res. 107, 10.1029/2001JD000327.

  • Neusüß, C., Wex, H., Birmili, W., Koziar, C., Busch, B., Brüggemann, E., Gnauk, T., Ebert, M., and Covert, D. S., 2002b: Characterization and parametrization of atmospheric particle number-, mass-, and chemical-size distributions in central Europe during LACE 98 and MINT, J. Geophys. Res. 107, 10.1029/2001JD000514. SIZE-RESOLVED AEROSOL CHARACTERIZATION FOR A POLLUTED EPISODE 155

  • Nunes, T. V. and Pio, C. A., 1993: Carbonaceous aerosols in industrial and coastal atmospheres, Atmos. Environ. 27, 1339–1346.

    Google Scholar 

  • Otto, M., 1995: Analytische Chemie, VCH-Verlag, Weinheim, New York, Basel, Cambridge, Tokio, pp. 24–30.

    Google Scholar 

  • Pakkanen, T. A., Kerminen, V. M., Hillamo, R. E., Makinen, M., Makela, T., and Virkkula, A., 1996: Distribution of Nitrate over sea salt and soil derived particles-implications from a field study, Atmos. Chem. 24, 189–205

    Google Scholar 

  • Pakkanen, T. A., Kerminen, V. M., Loukkola, K., Hillamo, R. E., Aarnio, P., Koskentalo, T., and Maenhaut, W., 2003: Size distribution of mass and chemical components in street-level and rooftop PM1 particles in Helsinki, Atmos. Environ. 37, 1673–1690

    Google Scholar 

  • Pelzing, M. and Herrmann, H., 1999: Application of Curie point pyrolysis-GC-MS for characterization of organic compounds in airborne particulate matter. Proc. of EUROTRAC Symposium '98, edited by P. M. Borell and M. Borell, WIT Southampton, UK, Vol. 1, pp. 634–638.

    Google Scholar 

  • Penner, J. E. and Novakov, T., 1996: Carbonaceous particles in the atmosphere: ahistorical perspective to the Fifth International Conference on Carbonaceous Particles in the Atmosphere, J. Geophys. Res. 101, 19373–19378.

    Google Scholar 

  • Perrino, C., Catrambone, M., Di Menno DiBucchianico, A., and Allegrini, I., 2002: Gaseous ammonia in the urban area of Rome, Italy and its relationship with traffic emissions, Atmos. Environ. 36, 5385–5394.

    Google Scholar 

  • Petzold, A. and Nießner, R., 1996: Coulometrische Messung der Rußbelastung in der Außenluft-Verfahrensentwicklung und Anwendung an Meßstellen unterschiedlicher Belastung, Gefahrstoffe-Reinhaltung der Luft 56, 173–177.

    Google Scholar 

  • Plewka, A., 2001: Untersuchungen zum Anteil mittelflüchtiger organischer Verbindungen im urbanen troposphärischen Aerosol. Ph. D. Thesis, Universität Leipzig, pp. 135.

  • Raes, F., Bates, T., McGovern, F., and Van Liederke, M., 2000: The second aerosol characterization experiment (ACE-2): General overview and main results, Tellus 52B, 111–125.

    Google Scholar 

  • Rogge, W. F., Hildemann, L. M., Mazurek, M. A., Cass, G. R., and Simoneit, B. R. T., 1991: Sources of fine organic aerosol, 1. Charbroilers and meat cooking operations, Environ. Sci. Technol. 25, 1112–1125.

    Google Scholar 

  • Rogge, W. F., Hildemann, L. M., Mazurek, M. A., and Cass, G. R., 1993: Sources of fine organic aerosol, 2. Noncatalyst and catalyst-equipped automobiles and heavy duty diesel trucks, Environ. Sci. Technol. 27, 636–651.

    Google Scholar 

  • Rogge,W. F., Mazurek, M., Hildemann, L. M., and Cass, G. R., 1993a: Quantification of urban organic aerosols at a molecular level: Identification, abundance and seasonal variation, Atmos. Environ. 27, 1309–1330.

    Google Scholar 

  • Satsumabayashi, H., Kurita, H., Yokouchi, Y., and Ueda, H., 1989: Mono-and dicarboxylic acids under long range transport of air pollution in Central Japan, Tellus 41B, 219–229.

    Google Scholar 

  • Satsumabayashi, H., Kurita, H., Yokouchi, Y., and Ueda, H., 1990: Photochemical formation of particulate dicarboxylic acids under long range transport in Central Japan, Atmos. Environ. 24A, 1430–1450.

    Google Scholar 

  • Schmid, H., Laskus, L., Abraham, H. J., Baltensperger, U., Lavanchy,V., Bizjak, M., Burba, P., Cachier, H., Crow, D., Chow, J., Gnauk, T., Even, A., ten Brink, H. M., Giesen, K. P., Hitzenberger, R., Hueglin, C., Maenhaut,W., Pio, C., Carvalho, A., Putaud, J. P., Toom-Sauntry, D., and Puxbaum, H., 2001. Results of the "carbon conference" international aerosol carbon round robin test stage I, Atmos. Environ. 35, 2111–2121.

    Google Scholar 

  • Schneider, J. K., Gagosian, R. B., Cochran, J. K., and Trull, T.W., 1983: Particle size distributions of n-alkanes and 210Pb in aerosols off the coast of Peru, Nature 304, 429–432.

    Google Scholar 

  • Shah, J. J. and Rau, J. A., 1991: Carbonaceous species methods comparison study: Interlaboratory round robin interpretation of results. Research Division, California Air Resources Board, Final Report G2E-0024, Sacramento, CA.

    Google Scholar 

  • Simoneit, B. R. T., 1984: Organic matter of the troposphere III. Characterization and sources of petroleum and pyrogenic residues in aerosols over the western United States, Atmos. Environ. 18, 51–67.

    Google Scholar 

  • Spindler, G., Mölders, N., Hanß, J., Beier, N., and Kramm, G., 1996: Determining the dry deposition of SO2, O3, NO und NO2 at the SANA core station Melpitz, Meteorol. Zeitschr. 5, 205–220.

    Google Scholar 

  • Spindler, G., Müller, K., and Herrmann, H., 1999: Main particulate matter components in Saxony (Germany). Trends and sampling aspects, ESPR-Environ. Sci. and Poll. Res. 6, 89–94.

    Google Scholar 

  • Spindler, G., Müller, K., Brüggemann, E., Gnauk, T., and Herrmann, H., 2003: Long-term sizesegregated characterization of PM10, PM2.5 and PM1 at the research station Melpitz downwind of Leipzig (Germany) using high and low volume filter samplers. Atmos. Environ. (accepted).

  • Statistical Yearbook for the Federal Republic of Germany, 1998. Ed.: Federal Statistical Office.

  • Stuttgart Stephanou, E. G., 1992: a.?-dicarboxylic acid salts and a.?-dicarboxylic acids, Naturwissenschaften 79, 128–131.

    Google Scholar 

  • Stohl, A., 1998: Computation, accuracy and applications of trajectories: A review and bibliography, Atmos. Environ. 32, 947–966.

    Google Scholar 

  • Strogies, M. and Kallweit, D., 1995: Nitrogen emissions in Germany and the potential for their reduction, Proc. International Conference on atmospheric ammonia emission, deposition, and environmental impacts. Culham, Oxford. Poster Proceedings (Eds.: M. Sutton et al.), 53–56. VDI 2449 Part 1. Prüfkriterien von Meßverfahren, Ermittlung von Verfahrenskenngrößen für die Messung gasförmiger Schadstoffe (Immission). VDI 2465 Part 2, 1999: Measurement of soot (Ambient Air), Themographic determination of Elemental Carbon after Thermal Desorption of Organic Carbon. VDI/DIN-Handbuch Reinhaltung der Luft, Band 4.

    Google Scholar 

  • Warneck, P., 2000: Chemistry of the Natural Atmosphere, 2nd Edition, Academic Press, San Diego, CA.

    Google Scholar 

  • Warneck, P., 2003: In-cloud chemistry opens pathway to the formation of oxalic acid in the marine atmosphere, Atmos. Environ. 37, 2423–2427.

    Google Scholar 

  • Yao, X., Fang, M., and Chan, C. K., 2002: Size distributions and formation of dicarboxylic acids in atmospheric particles, Atmos. Environ. 36, 2099–2107.

    Google Scholar 

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Authors and Affiliations

  1. Leibniz – Institut fü, r Troposphärenforschung, Permoserstrasse, 15, D-04318, Leipzig, Germany

    A. Plewka, T. Gnauk, E. Brüggemann, C. Neusüss & H. Herrmann

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  1. A. Plewka
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  2. T. Gnauk
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  3. E. Brüggemann
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  4. C. Neusüss
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Plewka, A., Gnauk, T., Brüggemann, E. et al. Size-Resolved Aerosol Characterization for a Polluted Episode at the IfT Research Station Melpitz in Autumn 1997. Journal of Atmospheric Chemistry 48, 131–156 (2004). https://doi.org/10.1023/B:JOCH.0000036843.29636.95

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