Skip to main content
SpringerLink
Log in

Structure of the adduct of bis(2,2′biimidazole)copper(II) perchlorate with 4,7-dihydro-1,2,4-triazolo[1,5-a]pyrimidine-7-one

  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

The crystal structure of the compound [Cu(biim)2](ClO4)2(7HtpO)2 (where 7HtpO is 4,7-dihydro-1,2,4-triazolo[1,5-a]pyrimidine-7-one and biim is 2,2'biimidazole) has been determined at room temperature. The dark green crystals are monoclinic, space group C2/c with unit dimensions a = 19.666(2) Å, b = 11.7586(8) Å, c = 13.4808(9) Å, β = 103.690(8)°, Z = 4, and Dx = 1.761 Mg-m−3. The structure was refined by a full-matrix least-squares procedure on F 2 to final R = 0.0806 using 4407 reflections. The cation is slightly distorted square planar and 7HtpO is not directly linked to the metal, the interaction between the cation and the triazolopyrimidine moiety taking place via stacking.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Salas, J.M.; Romero, M.A.; Sánchez, M.P.; Quirós, M. Coord. Chem. Rev. 1999, 193, 1119.

    Google Scholar 

  2. Abul Haj, M.; Quirós, M.; Salas, J.M.; Dobado, J.; Molina, J.; Basallote, M.G.; Máñez, M. Á., Eur. J. Inorg. Chem. 2002, 811.

  3. Abul Haj, M.; Salas, J.M.; Quirós, M.; Molina, J.; Faure, R. J. Mol. Struct. 2000, 519, 165.

    Google Scholar 

  4. Sheldrick, G.M. SHELX97, Program for Crystal Structure Refinement; University of Gottingen: Germany, 1997.

    Google Scholar 

  5. Hall, S.R.; du Boulay, D. XtalGX; University of Western Australia: Australia, 1997.

    Google Scholar 

  6. Bencini, A.; Mani, F. Inorg. Chim. Acta 1988, 154, 215.

    Google Scholar 

  7. Navarro, J.A.R.; Romero, M.A.; Salas, J.M.; Molina, J.; Tiekink, E.R.T. Inorg. Chim. Acta 1998, 274, 53.

    Google Scholar 

  8. Abul Haj, M.; Quirós, M.; Salas, J.M. Acta Crystallogr. 2003, E59, m903.

    Google Scholar 

  9. Roesky, H.W.; Andruh, M. Coord. Chem. Rev. 2003, 236,91.

    Google Scholar 

  10. Janiak, C. J. Chem. Soc., Dalton Trans. 2000, 3885.

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry and Chemical Technology, College of Science and Technology, Al-Quds University, Abu Dis, Jerusalem, Palestine

    Mohammad Abul Haj

  2. Departamento de Química Inorgánica, Facultad de Ciencias, Universidad de Granada, Granada, 18071, Spain

    Miguel Quirós & Juan M. Salas

Authors
  1. Mohammad Abul Haj
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Miguel Quirós
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Juan M. Salas
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Haj, M.A., Quirós, M. & Salas, J.M. Structure of the adduct of bis(2,2′biimidazole)copper(II) perchlorate with 4,7-dihydro-1,2,4-triazolo[1,5-a]pyrimidine-7-one. Journal of Chemical Crystallography 34, 549–552 (2004). https://doi.org/10.1023/B:JOCC.0000042024.70444.a0

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JOCC.0000042024.70444.a0

Search

Navigation