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A new phase of the complex trinitratotris (triphenylphosphineoxide)neodymium(III)

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Abstract

The crystal structure of the complex [Nd(NO3)(OPPh3)] (1) was obtained by single-crystal X-ray diffraction. The central neodymium(III) ion is nine coordinate arranged in a tricapped trigonal prism geometry. Crystallization of 1 occurs in the centrosymmetric monoclinic space group P21/c (No. 14) with a = 14.6496(9), b = 18.4506(11), c = 20.5491(11); β = 102.925(3)°; and Z = 4.

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Authors and Affiliations

  1. Department of Chemistry and Biochemistry, Baylor University, Waco, Texas, 76798-7348, U.S.A

    Rodney P. Feazell & Kevin K. Klausmeyer

  2. Department of Chemistry, The University of Texas at Tyler, Tyler, Texas, 75799, U.S.A

    John Brannon Gary & Ching Wah Wong

  3. Department of Chemistry, University of Nebraska, Lincoln, Nebraska, 68588-0304

    Jason A. Kautz

Authors
  1. Rodney P. Feazell
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  2. John Brannon Gary
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  3. Kevin K. Klausmeyer
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  4. Jason A. Kautz
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  5. Ching Wah Wong
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Feazell, R.P., Gary, J.B., Klausmeyer, K.K. et al. A new phase of the complex trinitratotris (triphenylphosphineoxide)neodymium(III). Journal of Chemical Crystallography 34, 507–511 (2004). https://doi.org/10.1023/B:JOCC.0000042018.24840.c5

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  • DOI: https://doi.org/10.1023/B:JOCC.0000042018.24840.c5

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