Abstract
A new dithioether silver(I) complex, {[Ag(L)1.5]NO3} n (1) has been prepared by the reaction of AgNO3 with 1,3-bis(benzylthio)propane (L) in methanol/chloroform. The structure was characterized by single-crystal X-ray diffraction analysis: rhombohedral system, space group R −3c, with a =b = 15.651(7), c = 39.26(4) Å, V = 8328(1) Å3, and Z = 6. The crystal structure consists of [Ag(L)1.5]+ cations and NO3 − anions. In 1, each silver(I) center is coordinated equivalently to three sulfur donors from three different ligands to give a trigonal-planar coordination geometry. Each L links two adjacent silver(I) centers in bis-monodentate bridging mode to form a 2D (6,3) network sheet. Furthermore, these 2D sheets are linked by the weak coordination interactions between nitrate ions and silver(I) atoms to form a 3D brick-wall framework.
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Li, JR., Zhang, RH. & Bu, XH. Synthesis and crystal structure of a 2D (6,3) coordination network, {[Ag(L)1.5]NO3} n [L = 1,3-bis(benzylthio)propane]. Journal of Chemical Crystallography 34, 501–505 (2004). https://doi.org/10.1023/B:JOCC.0000042017.66254.05
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DOI: https://doi.org/10.1023/B:JOCC.0000042017.66254.05