Abstract
The title compound [(VO)(H2O)2(SeO3)]2[(H2pipe)SO4] was synthesized under hydrothermal condition with VOSO4, piperazidine (pipe), and SeO2, and its crystal structure was established using single-crystal X-ray diffraction method. The title compound was characterized with IR□Fluorescence. The crystal data: P-1 (No. 2), a = 8.633(2) Å, b= 9.223(2) Å, c= 12.508(3) Å, α =109.28(3)°, β =90.42(3)°, γ = 107.79(3)°, Mr = 644.08, V=888.5(3) Å3, Z=2, Dc = 2.407 g cm−3, μ =5.350 mm−1, F(000)=632. The structure of the title compound consists of an infinite neutral ladder chain, which is built up from VO6 octahedral and SeO3 pyramidal units sharing vertices, and organic salt. The biprotonized pipe (piperazidine) and SO4 2− interact with one another and the inorganic chain through strong hydrogen bonds N–H···O or O–H···O to give a 3D structure. Hydrogen bonds play a role of stabilization structure.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
References
Zhang, Y.-P.; Jeffrey, T.D.; DeBord, C.J.O.; Connor, R.C.; Haushalter, A.C.; Zubieta, J. Angew. Chem. Int. Engl. 1996, 35, 989.
Zheng, L.-M.; Tabatha, W.; Wang, X.-Q.; Allan, J.J. Angew. Chem. Int. Ed. 2000, 39, 4528.
Zhang, L.-R.; Zhan, L.-R.; Yang, G.-Y.; Chen, X.-M.; Hua, S.-H. J. Chem. Soc. Dalton Trans. 2000, 275–278.
Wang, X.; Liu, L.; Jacobson, A.; Ross, K. J. Mater. Chem. 1999, 9, 859.
Li, G.-H.; Zhan, S.; Xu, Y.-H.; Feng, S.-H. Inorg. Chem. 2003, 42, 1170–1174.
Vaughey, J.T.; Harrison, W.T.A.; Dussack, L.L.; Jacobson, A. Inorg. Chem. 1994, 33, 4370–4375.
Kwon, Y.U.; Lee, K.-S.; Kim, Y.-H. Inorg. Chem. 1996, 35, 1161–1167.
Harrison, W.T.A.; Dussack, L.L.; Jacobson, A.J. Acta Crystallagr. 1995, C51, 2473–2476.
Guohe, H.; Jack, W.J.; Allan, J.J.; David, P.G. Chem. Mater. 1991, 3, 539–541.
Halasyamini, P.S.; O'Hare, D. Inorg. Chem. 1997, 36, 6409–6412.
Lee, K.-S.; Kwon, Y.-U.; Namgung, H.; Kim, S.-W.; Kwon, Y.-U.; Han, O.H. Inorg. Chem. 1996, 35, 7394–7398.
Kim, Y.H.; Lee, K.-S.; Kwon, Y.-U.; Han, O.H. Inorg. Chem. 1996, 35, 7394–7398.
Kim, Y.-T.; Kim, Y.-H.; Park, K.; Kwon, Y.-U.; Young, V.G. J. Solid State. Chem. 2001, 161, 23–30.
Kim, Y.H.; Kwon, Y.-U.; Lee, K.-S. Bull. Korean Chem. Soc. 1996, 17, 1123.
Nakano, H.; Ozeki, T.; Yagasaki, A. Inorg. Chem. 2001, 40, 1816–1819.
Zhimin, D.; Zhan, S.; Guanghua, L.; Xiaobo, C.; Xiaoying, L.; Yaohua, X.; Shouhua, F. J. Solid State Chem. 2003, 172, 205–211.
Intyaj, P.; Amitava, C.; Rao, C.N.R. Inorg. Chem. 2003, 42, 409–425.
Zhimin, D.; Xiaobo, C.; Zhan, S.; Dong, Z.; Guanghua, L.; Shouhua, F. Inorg. Chem. 2003, 42(3), 908–912.
Zhimin, D.; Zhan, S.; Guanghua, L.; Dong, Z.; Wensheng, F.; Haiying, J.; Wei, X.; Shouhua, F. Inorg. Chem. 2003, 42(3), 7396–7402.
Sheldrick, G.M. SHELX-97, Program for Crystal Structure Refinement [CP]; University of Gottingen: Germany, 1997.
Sheldrick, G.M. SHELX-97, Program for Crystal Structure Solution [CP]; University of Gottingen: Germany, 1997.
Adair, B.A.; de Delgado, G.D.; Delgado, J.M.; Cheetham, A.K. Angew. Chem. Int. Ed. 2000, 39, 745–747.
Fischer, R.; Kondrashev, Y.D. Handbook of Geochemistry; Springer-Verlag: New York, 1974.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Lian, Z., Huang, C., Zhang, H. et al. A novel vanadyl selenite templated by organic salt: [(VO)(H2O)2(SeO3)]2[(H2pipe)SO4]. Journal of Chemical Crystallography 34, 489–494 (2004). https://doi.org/10.1023/B:JOCC.0000042015.49290.a4
Issue Date:
DOI: https://doi.org/10.1023/B:JOCC.0000042015.49290.a4