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Assembly of selenoniobate–vanadoniobate double-anion heteropolyoxoniobate: synthesis, structure, and magnetic property

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Abstract

Recently, continuous interests and persisting efforts on heteropolyniobate have been dedicated to its preparation and exploration. In this work, a novel Se-centred heteropolyniobate, [H2SeNb12(VO)4O40][Cu(en)2]2{[VNb12(VO)4O40][Cu(en)2]4}0.5·39H2O (en = ethanediamine), was synthesized. The compound was synthesized in aqueous solution by reacting the K7HNb6O19·13H2O with a mixture of vanadate (V) and selenite (IV) source, which consists of two polyanions, i.e., V-centred one and Se-centred another. The architecture was characterized by infrared spectra, thermogravimetric analysis, X-ray powder diffraction spectroscopy, ultraviolet–visible and X-ray photoelectron spectroscopy. Further, the magnetic property shows the antiferromagnetic interaction of the compound.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (22071045, 21671056), the Program for Science and Technology Innovation Talents in Universities of Henan Province (19HASTIT044), Excellent Youth Science Fund Project of Henan Province (202300410042). Dongdi Zhang thanks for the Start-Up Fund of Henan University. Z. Liang is thankful to the Horizontal Cooperation Project of Nantong University (20ZH104), Science and Technology Program of Nantong (JC2020126), Project on the Cooperation of Industry, Education and Research of Jiangsu Province (BY2020556).

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Authors and Affiliations

  1. School of Textiles and Clothing, Nantong University, Nantong, 226019, China

    Zhi-Jie Liang & Hai-Bing Cheng

  2. Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, 475004, China

    Nan Li, Wei-Xin Du, Guan Wang & Dong-Di Zhang

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  1. Zhi-Jie Liang
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  2. Nan Li
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Contributions

Z-JL, NL and D-DZ wrote the draft; H-BC and W-XD collected the data; GW and D-DZ contributed to conceived the idea of the study. All authors contributed to the writing and revisions.

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Correspondence to Guan Wang or Dong-Di Zhang.

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Liang, ZJ., Li, N., Cheng, HB. et al. Assembly of selenoniobate–vanadoniobate double-anion heteropolyoxoniobate: synthesis, structure, and magnetic property. Tungsten 5, 75–80 (2023). https://doi.org/10.1007/s42864-022-00146-5

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