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Crystal structure of a nickel(II) complex with macrocyclic tetraamine

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Abstract

A new compound [Ni(cyclen)(η2-CH3CO2)]BF4 (cyclen = 1,4,7,10-tetraazacyclodode- cane) has been synthesized and characterized structurally. It crystallizes in the orthorhombic system, space group Pnnm with a =12.045(5), b =14.906(6), c =8.913(4) Å, V =1600.4(12) Å3, and Z =4. The nickel(II) ion has a distorted octahedral geometry with four secondary amines of the macrocycle and two oxygen atoms of the bidentate acetate group. TGA curve shows its thermal stability is up to 280°C.

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Authors and Affiliations

  1. Institute of Molecular Science, Shanxi University, Taiyuan, 030006, People's Republic of China

    Jun Li & Pin Yang

  2. Chemistry Department, Northwest University, Xi'an, 710069, People's Republic of China

    Jun Li, Yan-Wei Ren & Jin-Hua Zhang

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  1. Jun Li
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  2. Yan-Wei Ren
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  3. Jin-Hua Zhang
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  4. Pin Yang
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Correspondence to Jun Li.

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Li, J., Ren, YW., Zhang, JH. et al. Crystal structure of a nickel(II) complex with macrocyclic tetraamine. Journal of Chemical Crystallography 34, 409–413 (2004). https://doi.org/10.1023/B:JOCC.0000035380.06741.4e

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  • DOI: https://doi.org/10.1023/B:JOCC.0000035380.06741.4e

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