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Synthesis and crystal structure of trans-bis(O, O′-diisopropylthiophosphoryl-1H-imidazole-N3) bis(O,O′-diisopropyldithiophosphato) nickel(II) complex: Ni[N3-ImSP(OiPr)2]2[S2P(OiPr)2]2 (Im = imidazole; iPr = isopropyl)

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Abstract

The mononuclear complex, Ni[N3-ImSP(OiPr)2]2[S2P(OiPr)2]2 (Im = imidazole; iPr = isopropyl), was unexpectedly obtained in a reaction of bis(O,O′-diisopropyl-dithiophosphato) nickel(II) complex with imidazole ligand, and its structure was determined by X-ray crystallography. It crystallizes in the triclinic system, space group P \(\overline {\text{1}} \), with lattice parameters a = 12.437(3) Å, b = 13.181(3) Å, c = 8.4580(17) Å, α = 93.16(3)°, β = 101.93(3)°, β = 65.26(3)°, and Z = 1. The Ni atom has almost perfect octahedral coordination geometry and is coordinated by two N atoms of imidazole from two O,O′-diisopropylthiophosphoryl-1H-imidazole ligands in axial positions and four S atoms from two (O,O′-diisopropyldithiophosphato) anions which act as bidentate ligands forming a four-membered chelate ring in the equatorial plane. The Ni—S bond distances are 2.469(1) and 2.507(1) Å, and the Ni—N bond distances are 2.097(2) Å. The IR spectra data are in agreement with the structural data.

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Authors and Affiliations

  1. New Materials & Function Coordination Chemistry Laboratory, Qingdao University of Science and Technology, Qingdao, 266042, People's Republic of China

    Fangfang Jian, Kui Jiao, Qingxiang Wang & Huanxiang Wang

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  1. Fangfang Jian
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  2. Kui Jiao
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  3. Qingxiang Wang
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  4. Huanxiang Wang
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Correspondence to Kui Jiao.

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Jian, F., Jiao, K., Wang, Q. et al. Synthesis and crystal structure of trans-bis(O, O′-diisopropylthiophosphoryl-1H-imidazole-N3) bis(O,O′-diisopropyldithiophosphato) nickel(II) complex: Ni[N3-ImSP(OiPr)2]2[S2P(OiPr)2]2 (Im = imidazole; iPr = isopropyl). Journal of Chemical Crystallography 34, 147–151 (2004). https://doi.org/10.1023/B:JOCC.0000014702.90325.9d

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