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A crystallographic study of (2-acetylpyridine-κN 4-phenylthyosemicarbazonate-κ2N1,S) methyl-trans-dichlorotin(IV)

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Abstract

The preparation and characterization of [Sn(C14H13N4S)(CH3)Cl2], an organotin(IV) complex containing 2-acetylpyridine(4)-phenylthiosemicarbazone, is described. The molecular structure was studied by single crystal X-ray diffraction, and IR and Mössbauer spectroscopies. The title compound crystallizes in the centric triclinic space group, P \(\overline 1\), as discrete neutral complexes, with the Sn(IV) ion in a distorted octahedral coordination geometry, with the thiosemicarbazone derivative in a meridional configuration and the chlorides in trans positions.

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References

  1. Bamgboye, T.T.; Bamgboye, O.A. Inorg. Chim. Acta 1988, 144, 249.

    Google Scholar 

  2. Barbieri, R.S.; Beraldo, H.O.; Filgueiras, C.A.L.; Abras, A.; Nixon, J.F.; Hitchock, P.B. Inorg. Chim. Acta 1993, 206, 169.

    Google Scholar 

  3. Labib, L.; Khall, T.E.; Iskander, M.F.; Refaat, L.S. Polyhedron 1996, 15, 349.

    Google Scholar 

  4. Francisco, R.H.P.; Gambardella, M.T.P.; Sousa, G.F.; Abras, A. Acta Cryst. 2000, C56, 187.

    Google Scholar 

  5. Enraf-Nonius. CAD4 Express Software; Enraf-Nonius: Delft, The Netherlands, 1994.

    Google Scholar 

  6. Harms, K.; Wocadlo, S. XCAD-4, Program for Processing CAD-4 Diffractometer Data; University of Marburg: Germany, 1995.

    Google Scholar 

  7. Sheldrick, G.M. SHELXL97, Program for Crystal Structure Refinement; University of Göttingen: Germany, 1997.

    Google Scholar 

  8. Sheldrick, G.M. SHELXS97, Program for Crystal Structure Solution; University of Göttingen: Germany, 1997.

    Google Scholar 

  9. North, A.C.T.; Phillips, D.C.; Matthews, F.S. Acta Cryst. 1968, A24, 351.

    Google Scholar 

  10. Sousa, G.F.; Francisco, R.H.P.; Gambardella, M.T.P.; Santos, R.H.A.; Abras, A. J. Braz. Chem. Soc. 2001, 12 (6), 722.

    Google Scholar 

  11. Sousa, G.F.; Abras, A.; Filgueiras, C.A.L. In Proceedings of the International Conference on the Applications of the Mössbauer Effect; ICAME-95, Ortali, I. Ed.; SIR: Bologna, Italy, 1996; pp 79–82.

    Google Scholar 

  12. Farrugia, L.J. J. Appl. Cryst. 1997, 30, 565.

    Google Scholar 

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Authors and Affiliations

  1. Instituto de Química de São Carlos, Universidade de São Paulo, Caixa Postal 780, 13560-970, São Carlos, SP, Brazil

    Regina H. P. Francisco & M. Teresa do P. Gambardella

  2. Instituto de Química, ICC, Universidade de Brasília, 70910-900, Brasília, DF, Brazil

    Gerimário F. de Sousa

Authors
  1. Regina H. P. Francisco
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  2. M. Teresa do P. Gambardella
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  3. Gerimário F. de Sousa
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Francisco, R.H.P., Gambardella, M.T.d.P. & de Sousa, G.F. A crystallographic study of (2-acetylpyridine-κN 4-phenylthyosemicarbazonate-κ2N1,S) methyl-trans-dichlorotin(IV). Journal of Chemical Crystallography 34, 39–42 (2004). https://doi.org/10.1023/B:JOCC.0000014686.04680.31

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  • DOI: https://doi.org/10.1023/B:JOCC.0000014686.04680.31

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