Abstract
It is shown, using the WO3–diamond system as an example, that, during high-pressure sintering of diamond in the presence of nonmetallic catalysts, polycrystalline diamond consisting of submicron-sized crystallites is formed in pores of the compact. The elastic properties of the materials thus prepared suggest that WO3 has an advantageous effect on diamond sintering.
Similar content being viewed by others
REFERENCES
Ueda, F., Ohashi, T., Akaishi, M., and Yamaoka, S., Cutting Performance of Sintered Diamond with MgCO3 as a Sintering Agent, Mater. Sci. Eng., A, 1996, vol. 209, pp. 260–263.
Akaishi, M. and Yamaoka, S., Physical and Chemical Properties of the Heat Resistant Diamond Compacts from Diamond-Magnesium Carbonate System, Mater. Sci. Eng., A, 1996, vol. 209, pp. 54–59.
Astakhov, M.V., Ziganshina, R.N., and Shalimov, M.D., Mechanism of Gas-Phase-Assisted Diamond Formation at High Pressures and Temperatures, Izv. Vyssh. Uchebn. Zaved., Chern. Metall., 1993, vol. 3, pp. 15–18.
Khvostantsev, L.G., A Verkh-Niz (Up-Down) Toroid Device for Generation of High Pressure, High Temp.-High Pressures, 1984, vol. 16, no. 2, pp. 165–169.
Filonenko, V.P. and Zibrov, I.P., The Interaction between WO3 and Carbon under High Pressure, Proc. Joint 15th AIRAPT and 33rd EHPRG Int. Conf. on High Pressure Science and Technology (Warsaw, 1995), Singapore: World Sci., 1996, pp. 107–109.
Akaishi, M., New Non-Metallic Catalysts for the Synthesis of High Pressure, High Temperature Diamond, Diamond Relat. Mater., 1993, vol. 2, pp. 183–189.
Gigle, P.D., The Strength of Polycrystalline Diamond Compacts, Proc. 6th AIRAPT Int. Conf. on High-Pressure Science and Technology (Boulder, 1977), New York: Plenum, 1979, vol. 1, pp. 914–922.
Roberts, D.C., SYNDITE-Its Mechanical and Physical Properties, Ind. Diamond Rev., 1979, pp. 237–241.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Ekimov, E.A., Gierlotka, S., Zibrov, I.P. et al. Sintering of Diamond in the Presence of WO3 . Inorganic Materials 40, 595–599 (2004). https://doi.org/10.1023/B:INMA.0000031991.76372.f5
Issue Date:
DOI: https://doi.org/10.1023/B:INMA.0000031991.76372.f5