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Coordination State of Boron and Aluminum in Low-Alkali Aluminoborosilicate Glasses

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Abstract

The structure of aluminoborosilicate glasses is considered. It is found that the coordination states of boron and aluminum in glasses may vary depending on the composition, which has a perceptible effect on the properties of glaze glasses. Significant discrepancies were found between the experimental and calculated TCLE values of such glasses, which is due to a changed content of four-coordination boron and the emergence of six-coordination aluminum. Considering these data, it is possible to predict the physicochemical properties of glaze glasses.

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Authors and Affiliations

  1. Kazan State Power University, Kazan, Russia

    V. V. Gerasimov & O. V. Spirina

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  1. V. V. Gerasimov
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  2. O. V. Spirina
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Gerasimov, V.V., Spirina, O.V. Coordination State of Boron and Aluminum in Low-Alkali Aluminoborosilicate Glasses. Glass and Ceramics 61, 168–170 (2004). https://doi.org/10.1023/B:GLAC.0000043083.36991.df

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  • DOI: https://doi.org/10.1023/B:GLAC.0000043083.36991.df

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