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Structure of Bismuth-Borate Glasses with RO-Group Oxides According to IR Spectroscopy

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Data on the structure of bismuth-borate glasses containing oxides of group-II elements are presented. It is found that in all bismuth-borate glasses the boron ions are present in two coordination states, forming complexes comprised of [BO3] and [BO4] groups. Bi2O3 present in the glasses in amounts 20 – 40 wt.% does not show any active influence on the structural state of the boron ions. The primary bismuth-oxygen structural group is [BiO4].

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Authors and Affiliations

  1. Belorussian State Technological University, Minsk, Belarus

    N. M. Bobkova & E. E. Trusova

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  1. N. M. Bobkova
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  2. E. E. Trusova
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Correspondence to E. E. Trusova.

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Translated from Steklo i Keramika, No. 3, pp. 3 – 7, March, 2015.

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Bobkova, N.M., Trusova, E.E. Structure of Bismuth-Borate Glasses with RO-Group Oxides According to IR Spectroscopy. Glass Ceram 72, 79–82 (2015). https://doi.org/10.1007/s10717-015-9728-0

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  • DOI: https://doi.org/10.1007/s10717-015-9728-0

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