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Reactions of Amidines with 5-Methylene-1,3-dioxolan-2-ones

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Chemistry of Heterocyclic Compounds Aims and scope

Abstract

The composition and yields of the products from the reaction of 4,4-dialkyl-5-methylene-1,3-dioxolan-2-ones with amidines depend on the structure of the initial amidine and on the reaction conditions. 2-Aminopyridines lead to 3-substituted 4-hydroxy-4-methyloxazolidin-2-ones and 4-methylene-oxazolidin-2-ones and also to sym-carbamides. 2-Amino-4,6-dimethylpyrimidine leads to the corresponding 4-methyleneoxazolidin-2-one. 3-Aminothiazoles give linear oxourethanes and sym-carbamides.

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Authors and Affiliations

  1. N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991

    A. A. Bogolyubov, N. B. Chernysheva & V. V. Semenov

  2. A. N. Nesmeyanov Institute of Heteroorganic Compounds, Russian Academy of Sciences, Moscow, 119991

    V. V. Nesterov & M. Yu. Antipin

Authors
  1. A. A. Bogolyubov
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  2. N. B. Chernysheva
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  3. V. V. Nesterov
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  4. M. Yu. Antipin
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  5. V. V. Semenov
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Bogolyubov, A.A., Chernysheva, N.B., Nesterov, V.V. et al. Reactions of Amidines with 5-Methylene-1,3-dioxolan-2-ones. Chemistry of Heterocyclic Compounds 40, 992–1001 (2004). https://doi.org/10.1023/B:COHC.0000046687.48079.62

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  • DOI: https://doi.org/10.1023/B:COHC.0000046687.48079.62

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