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New Fullerene-Based Stationary Phases for Gas Chromatography

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Abstract

Regularities were revealed for the retention of different classes of organic compounds on stationary phases based on C60 and carbon nanotubes and on phases of mixed composition (C60 and dibenzo-24-crown-8, C60 and dibenzo-30-crown-10, and C60 and β-cyclodextrin) in gas chromatography. A synergistic effect was observed for the stationary phases of mixed composition. Quantitative estimation of the dispersion potential demonstrated that the C60-based stationary phase differs significantly from hydrocarbon adsorbents and more closely resembles nonpolar liquid stationary phases. Under the conditions of solid-phase microextraction, an adsorbing element based on fullerene C60 can be used for the preconcentration of aromatic hydrocarbons.

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  1. St. Petersburg State University, Universitetskii pr. 2, St. Petersburg, 198504, Russia

    L. A. Kartsova & A. A. Makarov

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  1. L. A. Kartsova
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  2. A. A. Makarov
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Kartsova, L.A., Makarov, A.A. New Fullerene-Based Stationary Phases for Gas Chromatography. Journal of Analytical Chemistry 59, 724–729 (2004). https://doi.org/10.1023/B:JANC.0000037276.52195.97

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  • DOI: https://doi.org/10.1023/B:JANC.0000037276.52195.97

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