Skip to main content
SpringerLink
Log in

Catalymetric Determination of Rhodium Based on the Reaction of the Oxidation of Triphenylamine-4-Sulfonic Acid by Sodium Periodate

  • Published:
Journal of Analytical Chemistry Aims and scope Submit manuscript

Abstract

The catalytic activity of rhodium(III) was studied in the reaction of the oxidation of triphenylamine-4-sulfonic acid by sodium periodate at pH ≈ 3. The dependence of the reaction rate on the technique of catalyst preparation, the presence of activators, the concentrations of the components, and the acidity and temperature of solutions was revealed. A sensitive and selective method for the catalymetric determination of rhodium(III) is proposed and tested with synthetic mixtures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

REFERENCES

  1. Perez-Bendito, D. and Silva, M., Kinetic Methods in Analytical Chemistry, New York: Ellis Horwood, 1988. Translated under the title Kineticheskie metody v analiticheskoi khimii, Moscow: Mir, 1991.

    Google Scholar 

  2. Mushtakova, S.P., Gumenyuk, A.P., Khmelev, S.S., and Batasheva, N.A., Zh. Anal. Khim., 1993, vol. 48, no. 7, p. 1218.

    Google Scholar 

  3. Mushtakova, S.P., Gumenyuk, A.P., Kozhina, L.F., and Shtykova, S.S., Zh. Anal. Khim., 1999, vol. 54, no. 7, p. 749.

    Google Scholar 

  4. Mushtakova, S.P., Gumenyuk, A.P., Kozhina, L.F., and Khmelev, S.S., Zh. Anal. Khim., 1996, vol. 51, no. 7, p. 768.

    Google Scholar 

  5. Mushtakova, S.P., Gumenyuk, A.P., Bilenko, O.A., et al., Zh. Anal. Khim., 1995, vol. 50, no. 7, p. 732.

    Google Scholar 

  6. Nikonorov, P.G., Kozhina, L.F., and Mushtakova, S.P., Novye dostizheniya v organicheskoi khimii (New Advances in Organic Chemistry), Saratov: Saratovsk. Gos. Univ., 1997, p. 75.

    Google Scholar 

  7. Syrokomskii, V.S. and Promenkova, N.N., Zh. Anal. Khim., 1947, vol. 2, no. 5, p. 247.

    Google Scholar 

  8. Karyakin, Yu.V. and Angelov, I.I., Chistye khimicheskie veshchestva (Pure Chemical Substances), Moscow: Khimiya, 1974.

    Google Scholar 

  9. Pilipenko, A.T., Sereda, I.P., and Maslei, N.N., Assortiment reaktivov na iridii (The Assortment of Reagents for Iridium), Moscow: NIITEKhIM, 1970.

    Google Scholar 

  10. Budarin, L.I. and Prik, K.E., Zavod. Lab., 1960, vol. 26, no. 8, p. 23.

    Google Scholar 

  11. Aleksenko, S.S., Gumenyuk, A.P., Mushtakova, S.P., and Timerbaev, A.R., Zh. Anal. Khim., 2002, vol. 57, no. 3, p. 262.

    Google Scholar 

  12. Ginzburg, S.I., Ezerskaya, N.A., Prokof'eva, I.V., Fedorenko, N.V., Shlenskaya, V.I., and Bel'skii, N.K., Analiticheskaya khimiya platinovykh metallov (The Analytical Chemistry of Platinum-Group Metals), Moscow: Nauka, 1972.

    Google Scholar 

  13. Holzbecher, Z., Divis, L., Kral, M., Sucha, L., and Vlacil, F., Organica Cinidla v Anorganicke Analyze (Organic Reagents in Inorganic Analysis), Praga: SNTL, 1975. Translated under the title Organicheskie reagenty v neorganicheskom analize, Moscow: Mir, 1979.

    Google Scholar 

  14. Zhitenko, L.P., Rysev, A.P., Zavel'eva, O.V., and Golovin, K.A., Zh. Anal. Khim., 1989, vol. 44, no. 8, p. 1462.

    Google Scholar 

  15. Zhitenko, L.P., Rysev, A.P., Romanovskaya, L.E., and Solomonov, V.A., Zh. Anal. Khim., 1990, vol. 45, no. 11, p. 2216.

    Google Scholar 

  16. Khomutova, E.G., Rysev, A.P., Solomonov, V.A., and Fedorina, L.I., Zh. Anal. Khim., 1994, vol. 49, no. 8, p. 854.

    Google Scholar 

  17. Fedorina, L.I., Levinson, N.A., Rysev, A.P., and Khomutova, E.G., Zh. Anal. Khim., 1996, vol. 51, no. 5, p. 518.

    Google Scholar 

  18. Fedorina, L.I., Khomutova, E.G., and Rysev, A.P., Zh. Anal. Khim., 1997, vol. 52, no. 8, p. 853.

    Google Scholar 

  19. Khomutova, E.G., Rysev, A.P., and Fedorina, L.I., Zh. Anal. Khim., 1997, vol. 52, no. 7, p. 756.

    Google Scholar 

  20. Morozova, R.P., Yatsimirskii, K.B., and Egorova, I.T., Zh. Anal. Khim., 1970, vol. 25, no. 10, p. 1954.

    Google Scholar 

  21. Tikhonova, L.P., Borkovets, S.N., and Revenko, L.N., Ukr. Khim. Zh., 1976, no. 8, p. 869.

  22. Tikhonova, L.P., Svarkovskaya, I.P., Fedotova, I.A., and Solov'eva, G.N., Zh. Anal. Khim., 1991, vol. 46, no. 6, p. 1176.

    Google Scholar 

  23. Kalinina, V.E., Lyakushina, V.M., and Rybina, A.E., Zh. Anal. Khim., 1978, vol. 33, no. 1, p. 125.

    Google Scholar 

  24. Pilipenko, A.T., Markova, L.V., and Kaplan, M.L., Zh. Anal. Khim., 1970, vol. 25, no. 12, p. 2412.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Chernyshevsky State University, ul. Astrakhanskaya 83, Saratov, 410026, Russia

    P. G. Nikonorov, S. P. Mushtakova, N. A. Burmistrova & L. F. Kozhina

Authors
  1. P. G. Nikonorov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. S. P. Mushtakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. N. A. Burmistrova
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. L. F. Kozhina
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Nikonorov, P.G., Mushtakova, S.P., Burmistrova, N.A. et al. Catalymetric Determination of Rhodium Based on the Reaction of the Oxidation of Triphenylamine-4-Sulfonic Acid by Sodium Periodate. Journal of Analytical Chemistry 59, 141–145 (2004). https://doi.org/10.1023/B:JANC.0000014740.79334.81

Download citation

  • Issue Date:

  • DOI: https://doi.org/10.1023/B:JANC.0000014740.79334.81

Keywords

Search

Navigation