Skip to main content
SpringerLink
Log in

Electrochemical Behavior of Gold in Aqueous Solutions of Spirocyclopentyl Malonyl Peroxide

  • COLLOID CHEMISTRY AND ELECTROCHEMISTRY
  • Published:
Russian Journal of Physical Chemistry A Aims and scope Submit manuscript

Abstract

The anodic behavior of gold in solutions containing spirocyclopentyl malonyl peroxide is studied via cyclic voltammetry. It is found that gold dissolves under anodic polarization with the formation of a complex of singly charged cations with spirocyclopentyl malonyl peroxide as a ligand. Gold in this case corrodes at lower potentials (about 500 mV) than in the supporting solution.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1.
Fig. 2.
Fig. 3.
Fig. 4.
Fig. 5.

Similar content being viewed by others

REFERENCES

  1. The Chemistry of Peroxides, Ed. by Z. Rappoport (Wiley, New York, 2006).

    Google Scholar 

  2. A. O. Terent’ev, M. M. Platonov, A. S. Kashin, et al., Tetrahedron 64, 7944 (2008).

    Article  Google Scholar 

  3. A. O. Terent’ev, M. M. Platonov, and A. V. Kutkin, Centr. Eur. J. Chem. 4, 207 (2006).

    Google Scholar 

  4. A. O. Terent’ev, M. M. Platonov, I. B. Krylov, et al., Org. Biomol. Chem. 6, 4435 (2008).

    Article  Google Scholar 

  5. N. Cowan, I. A. Yaremenko, I. B. Krylov, A. O. Terent’ev, and J. Keiser, Bioorg. Med. Chem. 23, 5175 (2015).

    Article  CAS  Google Scholar 

  6. V. A. Vil’, I. A. Yaremenko, A. I. Ilovaisky, and A. O. Terent’ev, Molecules 22, 1881 (2017).

    Article  Google Scholar 

  7. A. O. Terent’ev, A. V. Kutkin, N. A. Troizky, et al., Synthesis 13, 2215 (2005). https://doi.org/10.1055/s-2005-872093

    Article  CAS  Google Scholar 

  8. A. O. Terent’ev, V. A. Vil’, E. S. Gorlov, et al., Org. Chem. 81, 810 (2016).

    Article  Google Scholar 

  9. V. A. Vil’, G. D. Gomes, O. V. Bityukov, K. A. Lyssenko, et al., Angew. Chem., Int. Ed. Engl. 57, 3372 (2018). https://doi.org/10.1002/anie.201712651

    Article  CAS  Google Scholar 

  10. I. A. Yaremenko, A. O. Terent’ev, V. A. Vil’, et al., Chem.–Eur. J. 20, 10160 (2014).

    Article  CAS  Google Scholar 

  11. E. Horozova, N. Dimcheva, and Z. Jordanova, Bioelectrochemistry 58, 181 (2002).

    Article  CAS  Google Scholar 

  12. D. F. Laine, Ch. W. Roske, and I. F. Cheng, Anal. Chim. Acta 608, 56 (2008).

    Article  CAS  Google Scholar 

  13. B. N. Ferdousi, M. Islam, T. Okajima, and T. Ohsaka, Electrochim. Acta 53, 968 (2007).

    Article  CAS  Google Scholar 

  14. R. Baron, A. Darchen, and D. Hauchard, Electrochim. Acta 51, 1336 (2006).

    Article  CAS  Google Scholar 

  15. M. D. Vedenyapina, V. A. Vil’, A. O. Terent’ev, and A. A. Vedenyapin, Russ. Chem. Bull. 66, 2044 (2017).

    Article  CAS  Google Scholar 

  16. M. D. Vedenyapina, A. M. Skundin, V. A. Vil’, M. M. Kazakova, and Ya. A. Barsegyan, Russ. J. Phys. Chem. A 94, 859 (2020).

    Article  CAS  Google Scholar 

  17. L. D. Burke and P. F. Nugent, Gold Bull. 30 (2), 43 (1997).

    Article  CAS  Google Scholar 

  18. H. Angerstein-Kozlowska, B. E. Conway, B. Barnett, and J. Mozota, J. Electroanal. Chem. 100, 417 (1979).

    Article  CAS  Google Scholar 

  19. A. O. Terent’ev, V. A. Vil’, E. S. Gorlov, et al., Chem. Sel. 2, 3334 (2017). https://doi.org/10.1002/slct.201700720

    Article  CAS  Google Scholar 

  20. J. C. Griffith, K. M. Jones, S. Picon, et al., J. Am. Chem. Soc. 132, 14409 (2010).

    Article  CAS  Google Scholar 

  21. Z. Galus, Fundamentals of Electrochemical Analysis (Wiley, Chichester, New York, 1976).

    Google Scholar 

  22. A. P. Simakova, M. D. Vedenyapina, V. V. Kuznetsov, N. N. Makhova, and A. A. Vedenyapin, Russ. J. Phys. Chem. A 88, 331 (2014).

    Article  CAS  Google Scholar 

  23. C. M. Ferro, G. J. Calandra, and A.-J. Arvía, J. Electroanal. Chem. 65, 963 (1975).

    Article  CAS  Google Scholar 

Download references

Funding

This work was supported by the RF Ministry of Science and Higher Education.

Author information

Authors and Affiliations

  1. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119334, Moscow, Russia

    M. D. Vedenyapina, V. A. Vil’, M. M. Kazakova & Y. A. Barsegyan

  2. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

    A. M. Skundin

Authors
  1. M. D. Vedenyapina
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. M. Skundin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. V. A. Vil’
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. M. Kazakova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Y. A. Barsegyan
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to M. D. Vedenyapina, A. M. Skundin, V. A. Vil’, M. M. Kazakova or Y. A. Barsegyan.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Vedenyapina, M.D., Skundin, A.M., Vil’, V.A. et al. Electrochemical Behavior of Gold in Aqueous Solutions of Spirocyclopentyl Malonyl Peroxide. Russ. J. Phys. Chem. 95, 213–216 (2021). https://doi.org/10.1134/S0036024421010313

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0036024421010313

Keywords:

Search

Navigation