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Crystal structure of anhydrous bismuth iodate, Bi(IO3)3

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Abstract

Bismuth iodate was synthesized by precipitation from bismuth nitrate and iodic acid. The powder was dissolved in dilute nitric acid and single crystals were obtained by slow evaporation at 70°C. Bi(IO3)3 crystallizes in the monoclinic system, space group P21/n (N° 14), a = 8.8882(2) Å, b = 5.9445(2) Å, c = 15.2445(5) Å, β = 97.064(1) Å. BiO9 polyhedra are edge-connected forming chains parallel to the b axis; these chains are linked through (IO3) groups forming layers parallel to (101). The 3D framework is designed by linking these layers through long I–O bonds. DSC analysis shows a remarkable thermal stability.

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Authors and Affiliations

  1. Laboratoire de Sciences Fondamentales, Université de Laghouat, Laghouat, Algeria

    Bachir Bentria & Djamal Benbertal

  2. Laboratoire de Cristallographie associé à l', Université Joseph Fourier, CNRS, BP 166, 38042, Grenoble Cedex 9, France

    Muriel Bagieu-Beucher, René Masse & Alain Mosset

Authors
  1. Bachir Bentria
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  2. Djamal Benbertal
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  3. Muriel Bagieu-Beucher
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  4. René Masse
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  5. Alain Mosset
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Correspondence to Alain Mosset.

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Bentria, B., Benbertal, D., Bagieu-Beucher, M. et al. Crystal structure of anhydrous bismuth iodate, Bi(IO3)3 . Journal of Chemical Crystallography 33, 867–873 (2003). https://doi.org/10.1023/A:1027409929990

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