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Synthesis and Crystal Structure of the Double Polyphosphate CsMn(PO3)4

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Abstract

The double polyphosphate CsMn(PO3)4 was prepared by crystallization from molten polyphosphoric acids containing cesium and manganese cations, and its crystal structure was determined: monoclinic cell, sp. gr. P21 , Z = 2, a= 5.212 Å,b= 13.581 Å, c = 7.394 Å, β = 102.11°. This compound has no structural analogs.

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Murashova, E.V., Chudinova, N.N. Synthesis and Crystal Structure of the Double Polyphosphate CsMn(PO3)4. Inorganic Materials 36, 1277–1281 (2000). https://doi.org/10.1023/A:1026698118607

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