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Mixed-Cation Cyclohexaphosphates: Synthesis and Crystal Structure of CsCuInP6O18-II

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Abstract

The cyclohexaphosphates CsM2+AlP6O18 (M2+ = Ni, Cu, Co, Mn, Cd), CsM2+GaP6O18 (M2+ = Ni, Cu, Mn, Cd), CsM2+VP6O18 (M2+ = Ni, Co), CsM2+FeP6O18 (M2+ = Ni, Cu, Co, Mn), CsM2+MnP6O18 (M2+ = Mg, Co), CsM2+InP6O18 (M2+ = Ni, Co) (type I), CsCuInP6O18 , CsCuVP6O18 , CsNiMnP6O18 (type II), Cs3Cd3Fe(P6O18)2 , Cs3Cu3Mn(P6O18)2 , Cs3Mn3In(P6O18)2 , and Cs3Cd3In(P6O18)2 were prepared by crystallization from molten polyphosphoric acids. The crystal structure of CsCuInP6O18-II was determined: triclinic cell, sp. gr. P \(\bar 1\) , Z = 1, a= 5.1360 Å, b= 8.917 Å,c = 9.237 Å, α = 86.98°, β = 75.04°, γ = 73.53°.

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REFERENCES

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  1. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 117907, Russia

    E. V. Murashova & N. N. Chudinova

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  1. E. V. Murashova
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  2. N. N. Chudinova
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Murashova, E.V., Chudinova, N.N. Mixed-Cation Cyclohexaphosphates: Synthesis and Crystal Structure of CsCuInP6O18-II. Inorganic Materials 36, 1271–1276 (2000). https://doi.org/10.1023/A:1026646101768

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